赵晓科研成果

赵晓 ( 教授 ) 赞82 的个人主页 https://teachers.jlu.edu.cn/Zhao_Group/zh_CN/index.htm   教授 性别 : 男 学历 : 博士研究生毕业 学位 : 博士 在职信息 : 在职 所在单位 : 材料科学与工程学院 学科 : 材料物理与化学 个人简介 赵晓，吉林大学“唐敖庆学者”领军教授A岗，国家级青年人才，长白山特聘青年拔尖人才，博士毕业于中科院长春应化所，先后在新加坡国立大学，日本电气通信大学和SPring-8从事科研工作，2021年加入吉林大学，开展氢能、燃料电池和原位表征领域的工作，研究聚焦“催化中心的原位动态追踪与解析”和“高效膜电极的设计与制备”。研究特色是联用谱学电化学工具，以期在催化电极上同时获取催化性能、催化中心和中间体的原位动态演变信息，并结合理论光谱模拟计算，建立构效关系，进而指导催化剂和膜电极的可控制备。学术论文：截止2023年，以第一/通讯作者在Science, PNAS, JACS, AM和EES等国际主流刊物发表论文20余篇。在研项目：承担/参与国家基金委自然科学优秀青年项目（海外）和国家重点研发计划子项目等项目，在研经费累计500余万。招生招聘：课题组目前经费充足，每年均有硕博名额，欢迎同学们报考。1. 学位硕士，材料物理与化学专业2. 专业硕士，材料与化工专业3. 博士研究生，电化学、材料、物理等方向均可4. 博士后，新能源材料与器件方向，课题组常年高薪招聘博士后人才开展合作研究教育经历： 1. 2007-2013 中科院长春应化所，博士研究生2. 2003-2007 湘潭大学，学士工作经历：  1. 2021-至今 吉林大学，教授2. 2014-2020 日本电气通信大学，特任助理教授3. 2013-2014 新加坡国立大学，Research Fellow获奖荣誉： 1. 国家级高层次人才青年项目，20212. 首批长白山特聘青年拔尖人才，20213. 博士研究生国家奖学金, 2012 社会兼职：1. eScience 青年编委，2022-2. Renewables 青年编委，2023-课题方向： 1. 氢能与燃料电池电催化材料，包括HER, HOR OER, ORR2. 高效膜电极的制备与表征, 包括燃料电池和电解水器件3. 谱学电化学表征技术，包括XAFS，DEMS4. 电催化与电合成，包括CO2RR，N2RR5. 金属-空气电池在研项目（在研经费累计500余万）：1. 国家高层次人才青年项目，2022-20242. 国家重点研发子项目-高稳定低铱催化剂结构精准构筑于高一致性批量制备, 2021-20243. 吉林大学学科交叉青年创新团队-“绿氢”制备，2022-4. 中央高校优秀青年团队培育项目，2023-5. 吉林大学“碳中和”团队，2022-6. 吉林大学启动经费，2021-2025论文列表：* 通讯作者，# 共同一作# 202356. Tiantian Zhao#, Kai Chen#, Xiaochun Xu, Xinyi Li, Xiao Zhao*, Qinghai Cai, Ke Chu* and Jingxiang Zhao*, Homonuclear dual-atom catalysts embedded on N-doped graphene for highly efficient nitrate reduction to ammonia: From theoretical prediction to experimental validation, Applied Catalysis B: Environmental, 2023, 339, 123156.55. Fa Yang# , Ping Song#, Xin Ge, Yan Wang, Takao Gunji, Wei Zhang*, Xiao Zhao*, and Weilin Xu*, Operando analysis reveals potential-driven in situ formation of single-Fe-atom electrocatalysts for green production of ammonia, Proceedings of the National Academy of Sciences, 2023, 120, e2301011120.54. Xiao Zhao*, Shinobu Takao, Yusuke Yoshida, Takuma Kaneko, Takao Gunji, Kotaro Higashi, Tomoya Uruga, Yasuhiro Iwasawa*，Roles of structural defects in polycrystalline platinum nanowires for enhanced oxygen reduction activity, Appl. Catal. B, 2023, 324: 122268.53. Jinchang Fan#, Zhipeng Feng#, Yajing Mu, Xin Ge, Dewen Wang, Lei Zhang, Xiao Zhao, Wei Zhang, David J Singh, Jingyuan Ma, Lirong Zheng, Weitao Zheng*, Xiaoqiang Cui*, J. Am. Chem. Soc., 2023, DOI.org/10.1021/jacs.2c11692. # 202252. Jiandong Wu, Xiao Zhao*, Xiaoqiang Cui*, Weitao Zheng*, Emerging two-dimensional metallenes: Recent advances in structural regulations and electrocatalytic applications, Chinese J. Catal., 2023, 43(11): 2802-2814.51. Xiaowen Ruan, Zhongxu Wang, Zhong Wei, Haiyan Zhang, Lei Zhang, Xiao Zhao, David J Singh, Jingxiang Zhao*, Xiaoqiang Cui*, Weitao Zheng*, Appl. Surf. Sci., 2023, 601: 154294.50. Qi Hao#, Hai-xia Zhong#, Jia-zhi Wang#, Kai-hua Liu#, Jun-min Yan, Zhou-hong Ren, Na Zhou, Xiao Zhao, Hao Zhang, Dong-xue Liu, Xi Liu, Li-wei Chen, Jun Luo, Xin-bo Zhang*, Nickel dual-atom sites for electrochemical carbon dioxide reduction, Nature Synthesis, 2022, 1(9): 719-728.49. Jiandong Wu, Jinchang Fan*, Xiao Zhao, Ying Wang, Dewen Wang, Hongtai Liu, Lin Gu, Qinghua Zhang, Lirong Zheng, David J Singh, Xiaoqiang Cui*, Weitao Zheng, Atomically Dispersed MoOx on Rhodium Metallene Boosts Electrocatalyzed Alkaline Hydrogen Evolution, Angew. Chem. Int. Ed., 2022, 61(34): e202207512.48. Xingcheng Ma, Feng Wang, Dongxu Jiao, Dantong Zhang, Xiao Zhao, David J Singh, Jingxiang Zhao*, Xiaoqiang Cui*, Weitao Zheng, Room-temperature liquid metal synthesis of nanoporous copper-indium heterostructures for efficient carbon dioxide reduction to syngas, Sci. China Mater., 2022, 65(12): 3504-3512.47. Xiaowen Ruan, Xiaoqiang Cui*, Yi Cui, Xiaofeng Fan, Zhiyun Li, Tengfeng Xie, Kaikai Ba, Guangri Jia, Haiyan Zhang, Lei Zhang, Wei Zhang, Xiao Zhao, Jing Leng, Shengye Jin, David J Singh, Weitao Zheng, Favorable Energy Band Alignment of TiO2 Anatase/Rutile Heterophase Homojunctions Yields Photocatalytic Hydrogen Evolution with Quantum Efficiency Exceeding 45.6%, Adv. Energy Mater., 2022, 12(16): 2200298.  #202146. Xiao Zhao*, Takao Gunji, Fan Lv, Bolong Huang,* Rui Ding, Jianguo Liu*, Mingchuan Luo, Zhigang Zou, and Shaojun Guo*, Direct Observation of Heterogeneous Surface Reactivity and Reconstruction on Terminations of Grain Boundaries of Platinum, ACS Mater. Lett., 2021 3(5): 622-629. 45. Rongpeng Ma#, Ying Wang#, Guoqiang Li, Long Yang, Shiwei Liu, Zhao Jin, Xiao Zhao*, Junjie Ge*, and Wei Xing*, Tuning the oxidation state of Ru to surpass Pt in hydrogen evolution reaction, Nano Research, 2021, 14(11): 4321-4327.44. Ying Wang, Guangri Jia, Xiaoqiang Cui*, Xiao Zhao, Qinghua Zhang, Lin Gu, Lirong Zheng, Lu Hua Li, Qiong Wu, David J Singh, Daiju Matsumura, Takuya Tsuji, Yi-Tao Cui, Jingxiang Zhao*, Weitao Zheng, Coordination Number Regulation of Molybdenum Single-Atom Nanozyme Peroxidase-like Specificity, Chem, 2021, 7(2): 436-449. #202043. Meiling Xiao#, Zihao Xing#, Zhao Jin, Changpeng Liu, Junjie Ge, Jianbing Zhu*, Ying Wang*, Xiao Zhao*, and Zhongwei Chen*, Preferentially Engineering FeN4 Edge Sites onto Graphitic Nanosheets for Highly Active and Durable Oxygen Electrocatalysis in Rechargeable Zn-Air Batteries, Adv. Mater., 2020, 32(49): 2004900.42. Xin Luo, Xiaoqian Wei, Hengjia Wang, Wenling Gu, Takuma Kaneko, Yusuke Yoshida, Xiao Zhao*, Chengzhou Zhu*, Secondary-Atom-Doping Enables Robust Fe–N–C Single-Atom Catalysts with Enhanced Oxygen Reduction Reaction, Nano-Micro Lett., 2020, 12(1): 163. 41. Fang Luo#, Hao Hu#, Xiao Zhao#, Zehui Yang*, Quan Zhang, Jingxiang Xu*, Takuma Kaneko, Yusuke Yoshida, Chengzhou Zhu* and Weiwei Cai*, Robust and Stable Acidic Overall Water Splitting on Ir Single Atoms, Nano Lett., 2020，20(3): 2120-2128. IF 11.238.40. Xiao Zhao*#, Takao Gunji#, Takuma Kaneko#, Shinobu Takao, Tomohiro Sakata, Kotaro Higashi, Yusuke Yoshida, Junjie Ge, Changpeng Liu, Wei Xing*, Jianbing Zhu, Meiling Xiao, Tomoya Uruga, Franklin Feng Tao and Zhongwei Chen*, Evidence for Interfacial Geometric Interactions at Metal-Support Interfaces and Its Influence on the Electroactivity and Stability of Pt Nanoparticles, J. Mater. Chem. A, 2020, 8(3): 1368-1377.39. Xiao Zhao, Yutaka Hamamura, Yusuke Yoshida, Takuma Kaneko, Takao Gunji, Shinobu Takao, Kotaro Higashi, Tomoya Uruga, and Yasuhiro Iwasawa*, Plasma-Devised Pt/C Model Electrodes for Understanding the Doubly Beneficial Roles of a Nanoneedle-Carbon Morphology and Strong Pt-Carbon Interface in the Oxygen Reduction Reaction, ACS Appl. Energy Mater., 2020, 3(6): 5542-5551.38. Jianbing Zhu, Shuang Li, Meiling Xiao, Xiao Zhao, Gaoran Li, Zhengyu Bai, Matthew Li, Yongfeng Hu, Renfei Feng, Wenwen Liu, Rui Gao, Dong Su, Aiping Yu, Zhongwei Chen, Tensile-strained ruthenium phosphide by anion substitution for highly active and durable hydrogen evolution, Nano Energy, 2020, 77: 105212. #201937. Xinlong Tian#, Xiao Zhao#, Ya-Qiong Su#, Lijuan Wang, Hongming Wang, Dai Dang, Bin Chi, Hongfang Liu, Emiel J.M. Hensen, Xiong Wen (David) Lou*, and Bao Yu Xia*, Engineering Bunched PtNi Alloy Nanocages for Efficient Oxygen Reduction in Practical Fuel Cells, Science, 2019, 366(6467): 850-856. 36. Xiao Zhao*, Takao Gunji, Takuma Kaneko, Yusuke Yoshida, Shinobu Takao, Kotaro Higashi, Tomoya Uruga, Wenxiang He, Jianguo Liu*, Zhigang Zou, An Integrated Single-Electrode Method Reveals the Template Roles of Atomic Steps: Disturb Interfacial Water Networks and thus Affect the Reactivity of Electrocatalysts, J. Am. Chem. Soc., 2019, 141(21): 8516-8526.35. Xiao Zhao, Shinobu Takao, Takuma Kaneko, Yasuhiro Iwasawa, Key Factors for Simultaneous Improvements of Performance and Durability of Core-Shell Pt3Ni/Carbon Electrocatalysts Toward Superior Polymer Electrolyte Fuel Cell, Chem Rec, 2019, 19 (7): 1337-1353.34. Meiling Xiao#, Yongting Chen#, Jianbing Zhu#, Hao Zhang, Xiao Zhao, Liqin Gao, Xian Wang, Jin Zhao, Junjie Ge*, Zheng Jiang*, Shengli Chen*, Changpeng Liu and Wei Xing*, Climbing the Apex of the ORR Volcano Plot via Binuclear Site Construction: Electronic and Geometric Engineering, J. Am. Chem. Soc., 2019, 141(44): 17763-17770.33. Jiaxi Zhang, Xiao Zhao, Li Du, Yutao Li, Longhai Zhang, Shijun Liao, John B Goodenough, Zhiming Cui, Antiperovskite Nitrides CuNCo3–xVx: Highly Efficient and Durable Electrocatalysts for the Oxygen-Evolution Reaction, Nano Lett., 2019,19(10): 7457-7463. #201832. Shinobu Takao, Oki Sekizawa, Gabor Samjeské, Takuma Kaneko, Kotaro Higashi, Yusuke Yoshida*, Xiao Zhao, Tomohiro Sakata, Takashi Yamamoto, Takao Gunji, Tomoya Uruga, and Yasuhiro Iwasawa，Observation of Degradation of Pt and Carbon Support in Polymer Electrolyte Fuel Cell Using Combined Nano-X-ray Absorption Fine Structure and Transmission Electron Microscopy Techniques. ACS Appl. Mater. Interfaces, 2018 10(33): 27734-27744.31. Oki Sekizawa，Takuma Kaneko1，Kotaro Higashi1，Shinobu Takao1，Yusuke Yoshida, Takao Gunji，Xiao Zhao，Gabor Samjeské，Tomohiro Sakata，Tomoya Uruga，and Yasuhiro Iwasawa*, Key Structural Transformations and Kinetics of Pt Nanoparticles in PEFC Pt/C Electrocatalysts by a Simultaneous Operando Time-Resolved QXAFS–XRD Technique，Topics in Catalysis，2018，61(9): 889-901. #201730. Xiao Zhao, Shinobu Takao, Kotaro Higashi, Takuma Kaneko, Gabor Samjeskè, Oki Sekizawa, Tomohiro Sakata, Yusuke Yoshida, Tomoya Uruga, Yasuhiro Iwasawa*, Simultaneous Improvements in Performance and Durability of an Octahedral PtNix/C Electrocatalyst for Next-Generation Fuel Cells by Continuous, Compressive, and Concave Pt Skin Layers, ACS Catal., 2017, 7(7): 4642-4654. #201629. Jianbing Zhu, Meiling Xiao, Kui Li, Changpeng Liu, Xiao Zhao*, Wei Xing, Active Pt3Ni (111) Surface of Pt3Ni Icosahedron for Oxygen Reduction, ACS Appl. Mater. Interfaces, 2016, 8(44): 30066-30071.28. Takuma Kaneko, Gabor Samjeské, Shin-ichi Nagamatsu, Kotaro Higashi, Oki Sekizawa, Shinobu Takao, Takashi Yamamoto, Xiao Zhao, Tomohiro Sakata, Tomoya Uruga, and Yasuhiro Iwasawa*, Key Structural Kinetics for Carbon Effects on the Performance and Durability of Pt/Carbon Cathode Catalysts in Polymer Electrolyte Fuel Cells Characterized by In Situ Time-Resolved X-ray Absorption Fine Structure, J. Phys. Chem. C, 2016, 120(42): 24250-24264.27. Shinobu Takao, Oki Sekizawa, Gabor Samjeské, Shin-ichi Nagamatsu, Takuma Kaneko, Kotaro Higashi, Takashi Yamamoto, Kensaku Nagasawa, Xiao Zhao, Tomoya Uruga, Yasuhiro Iwasawa, Spatially non-uniform degradation of Pt/C cathode catalysts in polymer electrolyte fuel cells imaged by combination of nano XAFS and STEM-EDS techniques, Top Catal., 2016, 59(19): 1722-1731. #201526. Xiao Zhao*, Jian Zhang, Liangjun Wang, He Xing Li, Zhaolin Liu*, Wei Chen*, Ultrathin PtPdCu Nanowires Fused Porous Architecture with 3D Molecular Accessibility: An Active and Durable Platform for Methanol Oxidation, ACS Appl. Mater. Interfaces, 2015, 7(47): 26333-26339.25. Jianbing Zhu, Meiling Xiao, Xiao Zhao, Changpeng Liu, Wei Xing*, Titanium dioxide encapsulated in nitrogen-doped carbon enhances the activity and durability of platinum catalyst for Methanol electro-oxidation reaction. J. Power Sources, 2015, 292, 78-86.24. Jianbing Zhu, Meiling Xiao, Xiao Zhao, Changpeng Liu, Junjie Ge*, Wei Xing*, Strongly coupled Pt nanotubes/N-doped graphene as highly active and durable electrocatalysts for oxygen reduction reaction, Nano Energy, 2015, 13, 318-326.23. Jian Zhang, Liangjun Wang, Leilei Xu, Xiaoming Ge, Xiao Zhao, Min Lai, Zhaolin Liu* and Wei Chen*, Porous cobalt-manganese oxide nanocubes derived from metal organic frameworks as a cathode catalyst for rechargeable Li-O2 batteries, Nanoscale, 2015, 7 (2), 720-726.22. Liang Yan, Weiwei Cai, Xiao Zhao, Liang Liang,Wei Xing*, and Changpeng Liu*, Investigation of a New Method to Prepare Low Methanol and Water Crossover Membrane Electrode Assembly for Passive Direct Methanol Fuel Cells. Energy and Environment Focus, 2015, 4 (1), 1-7.21. Liang Jun Wang, Jian Zhang, Xiao Zhao, Lei Lei Xu, Zhi Yang Lyu, Min Lai and Wei Chen*, Palladium nanoparticle functionalized graphene nanosheets for Li-O2 batteries: enhanced performance by tailoring the morphology of the discharge product. RSC Adv., 2015, 5 (90), 73451-73456. #201420. Xiao Zhao, Jianbing Zhu, Liang Liang, Chenyang Li, Changpeng Liu*, Jianhui Liao, Wei Xing*, Biomass-derived N-doped carbon and its application in electrocatalysis, Appl. Catal. B, 2014, 154, 177-182. 19. Xiao Zhao, Zhang Jian, Liangjun Wang, Zhaolin Liu*, Wei Chen*, PdxCu100-x networks: an active and durable electrocatalyst for ethanol oxidation in alkaline medium, J. Mater. Chem. A, 2014, 2 (48), 20933-20938.18. Jianbing Zhu, Xiao Zhao, Meiling Xiao, Liang Liang, Changpeng Liu, Jianhui Liao, and Wei Xing*, The construction of nitrogen-doped graphitized carbon-TiO2 composite to improve the electrocatalyst for methanol oxidation. Carbon, 2014, 72, 114-124.17. Jianbing Zhu, Meiling Xiao, Xiao Zhao, Kui Li, Changpeng Liu, and Wei Xing*, Nitrogen-doped carbon–graphene composites enhance the electrocatalytic performance of the supported Pt catalysts for methanol oxidation. Chem. Commun., 2014, 50 (81), 12201-12203.16. Jian Zhang, Yubao Zhao, Xiao Zhao, Zhaolin Liu* and Wei Chen*, Porous Perovskite LaNiO3 Nanocubes as Cathode Catalysts for Li-O2 Batteries with Low Charge Potential, Scientific Reports, 2014, 4, 6005.15. Meiling Xiao, Songtao Li, Xiao Zhao, Jianbing Zhu, Min Yin, Changpeng Liu*, and Wei Xing*, Enhanced Catalytic Performance of Composition-Tunable PtCu Nanowire Networks for Methanol Electrooxidation. Chemcatchem, 2014, 6 (10), 2825-2831.14. Kui Li, Jianbing Zhu, Meiling Xiao, Xiao Zhao, Shikui Yao, Changpeng Liu*, and Wei Xing*, Promotion of Mesoporous Vanadium Carbide Incorporated on Resorcinol-Formaldehyde Resin Carbon Composites with High-Surface-Areas on Platinum Catalysts for Methanol Electrooxidation. Chemcatchem, 2014, 6 (12), 3387-3395. #201313. Xiao Zhao, Jianbing Zhu, Liang Liang, Chenyang Li, Changpeng Liu, Wei Xing, Surface reconstruction enhancing activity of Pt/C for formic acid electrooxidation by ultrasonic mixing with Pb/C and electrochemical activation process, Appl. Catal. B, 2013, 129, 146-152. IF 16.683.12. Xiao Zhao, Jianbing Zhu, Weiwei Cai, Meiling Xiao, Liang Liang, Changpeng Liu, Wei Xing, Pt-Pb hollow sphere networks: self-sacrifice-templating method and enhanced activity for formic acid electrooxidation, RSC Adv., 2013, 3 (6), 1763-1767. IF 3.119.11. Yang Hu, Xiao Zhao, Yunjie Huang, Qingfeng Li, Niels J. Bjerrum, Changpeng Liu*, Wei Xing*, Synthesis of self-supported non-precious metal catalysts for oxygen reduction reaction with preserved nanostructures from the polyaniline nanofiber precursor, J. Power Sources, 2013, 225, 129-136.10. Liang Yan, Jianhui Liao, Ligang Feng, Xiao Zhao, Liang Liang, Wei Xing*, and ChangpengLiu*, Developing and performance measurements for a novel miniaturized electrochemical methanol sensor, J. Electroanal. Chem., 2013, 688: 49-52. #20129. Xiao Zhao, Jianbing Zhu, Liang Liang, Changpeng Liu, Jianhui Liao, Wei Xing*, Enhanced electroactivity of Pd nanocrystals supported on H3PMo12O40/carbon for formic acid electrooxidation, J. Power Sources, 2012, 210, 392-396. 8. Xiao Zhao, Jianbing Zhu, Liang Liang, Jianhui Liao, Changpeng Liu*, Wei Xing*, Enhanced activity of Pt nanocrystals supported on a novel TiO2@ N-doped C nano-composite for methanol oxidation reaction, J. Mater. Chem., 2012, 22 (37), 19718-19725. 7. Xiao Zhao, Yang Hu, Liang Liang, Changpeng Liu, Jianhui Liao, Wei Xing, Ionic liquid-mediated synthesis of 'clean' palladium nanoparticles for formic acid electrooxidation, Int. J. Hydrog. Energy, 2012, 37 (1), 51-58.6. Shikui Yao, Ligang Feng, Xiao Zhao, Changpeng Liu, and Wei Xing*, Pt/C catalysts with narrow size distribution prepared by colloidal-precipitation method for methanol electrooxidation, J. Power Sources, 2012, 217, 280-286.5. Qing Lv, Min Yin, Xiao Zhao, Chenyang Li, Changpeng Liu*, and Wei Xing*, Promotion effect of TiO2 on catalytic activity and stability of Pt catalyst for electrooxidation of methanol. J. Power Sources, 2012, 218, 93-99.4. Ligang Feng, Shikui Yao, Xiao Zhao, Liang Yan, Changpeng Liu, and Wei Xing*, Electrocatalytic properties of Pd/C catalyst for formic acid electrooxidation promoted by europium oxide, J. Power Sources, 2012, 197, 38-43. #20113. Xiao Zhao, Min Yin, Liang Ma, Liang Liang, Changpeng Liu, Jianhui Liao, Tianhong Lu, Wei Xing, Recent advances in catalysts for direct methanol fuel cells, Energy Environ. Sci. 2011, 4 (8), 2736-2753.2. Ligang Feng, Xiao Zhao, Jing Yang, Wei Xing*, and Changpeng Liu, Electrocatalytic activity of Pt/C catalysts for methanol electrooxidation promoted by molybdovanadophosphoric acid. Catal. Commun., 2011, 14 (1), 10-14. #20101. Liang Ma, Xiao Zhao, Fengzhan Si, Changpeng Liu, Jianhui Liao, Liang Liang, and Wei Xing*, A comparative study of Pt/C and Pt-MoOx/C catalysts with various compositions for methanol electro-oxidation. Electrochim. Acta, 2010, 55 (28), 9105-9112.

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