唐浩东科研成果

个人简介 唐浩东，博士，教授，博导，1997年毕业于浙江工业大学工业分析专业，获学士学位。2007年毕业于浙江工业大学工业催化专业，获博士学位。2011-2012年作为访问学者在荷兰爱因霍芬理工大学访学一年。自2000年以来一直从事物理化学的教学科研工作，致力于物理化学及实验的教学改革工作，主持或参加国家级、省级、校教改项目及课程建设项目10余项，2021年获校第十届“我最喜爱的老师”（十佳）称号，是本校第一位实施“慕课西行”教师；所教授的物理化学课程于2020年获评省线上线下一流课程，2021年获评省线上一流课程和思政示范课程，2023年获评国家级线上线下一流课程。研究方向为工业催化（氟化工），现阶段研究课题主要有：氟化工铬系、铝系、镁系催化剂研究及工业化；活性炭负载的贵金属催化剂在加氢脱氯反应中的研究与工业化；铁基、钌基氨分解催化剂的研究及工业化；绿色甲醇催化剂的研究及工业化；含氟电子特气的研究与开发；贵金属催化剂的再分散及贵金属与载体SMSI研究。主持国家基金面上项目一项，主持横向项目8项，科研经费充足，在Nano Energy，Applied Catalysis B: Environmental等期刊上发表论文40余篇，授权专利20余项。与企业合作紧密，与三家上市公司有研发与工业化项目合作。今年研究生招生名额和学生意向基本确定。多谢报考，联系电话：18657108630（同微信）   以下为和衢州学院联培名额1个，指导教师：沈行加   副教授  主要研究方向：电化学，邮箱：shenhj@qzc.edu.cn2018年在中国科学院新疆理化技术研究所获得博士学位，2018 - 2021年在中科院宁波材料所从事博士后和助理研究员工作，2021年12月加入衢州学院。主要从事非贵金属电极材料的制备和应用研究，相关工作在Nature Materials, Angewandte Chemie, Nano Energy等期刊上发表文章50余篇。作为项目负责人主持国家/省自然科学基金青年项目各1项，博士后基金1项。代表性论文：1. Electrochimica Acta 2023,466, 143001.2. Small 2022,18, 2200730.3. Journal of Physical Chemistry Letters 2021,12 (1), 517-524.4. Journal of Materials Chemistry A 2021,9 (35), 19669.5. Chemical Engineering Journal 2021,404, 126462.6. Nature Materials 2020,19 (3), 282.7. Cell Reports Physical Science 2020,1 (11), 100255.8. Electrochemical Energy Reviews 2019,2 (2), 252–276.9. Angewandte Chemie-International Edition 2017,56 (44), 13800-13804.10. Nano Energy 2017,35, 9-16. 教学与课程 任现职以来，承担物理化学及物理化学实验的教学任务，年均教学工作量360当量学时，近5年累计获优课优酬奖励16次，连续5年获教学业绩考评优秀。坚持“以学生为中心”的教学理念，坚持教学改革创新，承担和参与各类教学改革/课程建设20余项，深得师生好评。取得以下进展：1、  首次开展慕课西行，教学中注重课程思政的隐形融入：2021年11月和塔里木大学、衢州学院开展慕课西行同步直播，为本校首次，至今开展同步直播48课时。同时开展跨校虚拟教研室活动3次，邀请专家讲座5人次，教学研讨3次，充分发挥院校特色，研讨教学改革，培训青年教师。在课程中隐形融入思政内容，将我国、我校和身边的重大科研成果等25个作为思政内容融入到课程案例教学和项目化教学内容中，激发学生爱国热情，培养学生科学精神和创新能力，课程2021年获评省首批思政示范课程。2、建立以学生为中心的教学理念，开展线上线下混合式教学：物理化学是化学化工等专业的核心课程，但课程难度大，学生学习积极性不佳。从2016年开始，对整个课程进行了混合式改革：对核心知识点用BOPPPS理念进行重构，拍摄微课视频90个，总时长近1000min，作为线上课程素材，课程已经在爱课程和省平台上线，2022年获评省线上一流课程；线下调整教学方法和模式，以学生为中心，提高课程两性一度作为课程改革的最终目标，强调采用互动、翻转教学。课程2021年获评省一流线上线下课程，2023年被评为国家级线上线下一流课程。试点班级学生学习积极性高，课堂活跃度大大增加，期末卷面成绩较其他班级高10-20分，课程得到学生普遍好评，2021年被评为校“我最喜爱的老师”称号。教学模式也得到省教指委赵雷洪教授认可，在2019年校本科评估总结会议上点评我的课程。3、  依托科研平台，对物理化学实验进行综合改革，提升课程高阶性和挑战度：针对实验内容陈旧，课程挑战度不够的问题，从2013年开始，依托科研平台尝试科研反哺，对物理化学实验进行综合性改革：调整基础物理化学实验教学时数，增加高阶性的综合物理化学实验：该实验学生自主查文献、制定实验计划、进行开题报告、实施实验、中期整改及最后PPT总结汇报。增加课程创新性和高阶性，提高课程的挑战度，大大提高学生综合能力。首届经该课程训练的学生在第7届省化学竞赛中，我院唯一两支一等奖队伍2位组长、4位成员（共获奖8人）都是综合实验班的学生，说明该课程改革成效显著。 科研项目 近5年承担的科研项目：1、Pd在氟氯烃气氛下的自/再分散及在烧结再生中的应用研究， 国家自然科学基金面上项目/纵向/IV类      2018.01-2021.12   71.7万，1/72、废弃氟氯烃（CFCs）的资源化利用及无害化处置，浙江省自然科学基金--公益项目/纵向/ VI类      2021.01-2023.12   10万，1/53、绿色甲醇合成催化剂中试及工业化放大（宁波中科远东催化工程技术有限公司与浙江工业大学合作共建），横向，2023-2033年，2000万，1/74、氨分解Ru基催化剂的中试及工业化，横向，2024-2029年，300万，1/6；5、SZ-001催化裂解制备SC-002催化技术  山东华夏神舟新材料有限公司/横向/VI类2020.04-2023.04     90万，1/46、山东东岳集团与浙江工业大学合作共建实验室框架协议  山东东岳集团、山东华夏神舟新材料有限公司/横向/V类         2019.07-2024.06     175万，1/37、固体催化剂制备氟乙烯（VF）的技术开发  金华永和氟化工有限公司/横向/ V类2021.12-2024.12     160万，1/48、不锈钢材质整套设备防腐蚀及在不同使用环境下延长使用寿命研究开发，浙江东田机械有限公司/横向/ VII类，2022.6-2024.6         40万，1/39、绿氨合成及氨分解中亚铁基铁催化剂中试及工业化开发，横向，2024-2026，840万，2/2010、超稳低汞聚氯乙烯合成催化剂工业试验与应用-氯乙烯单体合成用超稳低汞催化剂的研发内蒙古自治区科技重大专项/纵向/ IV类    2019.09-2023.09     332万，  3/6 11、乙炔氢氯化低汞催化剂的中试，贵州省铜仁市万山鸿发化工有限公司/横向/ V类，2015.09-2016.09    250万，   2/4 12、含氟电子气生产工艺中的催化剂开发，企业横向/ V类   2021.09-2025.09    150万，2/6      科研成果 近年来科研论文：2022年1、Ni, Ti-Tong; Meng, Yue; Koso, Aoki; Yao, Yi-Yang; Tang, Hao-Dong; Chen, Ai-Min; Xia, Sheng-Jie，Photocatalytic Degradation of Methylene Blue by Fe3O4@MAl-Layered Double Hydroxides (M=Zn, Co, Ni) Composite: Performance, Kinetics, and Mechanism，CHINESE JOURNAL OF INORGANIC CHEMISTRY，      38（9）1759-1770，SEP 2022；        2、Zhang, Lianyang; Meng, Yue; Koso, Aoki; Yao, Yiyang; Tang, Haodong; Xia, Shengjie，The mechanism of nitrogen reduction reaction on defective boron nitride (BN) monolayer doped with monatomic Co, Ni, and Mo-A first principles study，COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS ，647, 129072,  AUG 20 2022;        3、Zhang, Wujian; Meng, Yue; Liu, Yuhua; Shen, Hui; Ni, Zheming; Xia, Shengjie; Han, Wenfeng; Li, Ying; Tang, Haodong*，Boosted photocatalytic degradation of norfloxacin on LaOCl/LDH: Synergistic effect of Z-scheme heterojunction and O vacancies，JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING，10 (3), 107812,  JUN 2022;         4、Du, Yue; Zhao, Shaofen; Tang, Haodong; Ni, Zheming; Xia, Shengjie,  An active MoS2 with Pt-doping and sulfur vacancy for strengthen CO2 adsorption and fast Capture: A DFT approach,  CHEMICAL PHYSICS LETTERS,  802, 139784, SEP 2022;        5、Zhang, Wujian; Huang, Zhiling; Shen, Hui; Gu, Zhenhai; Xia, Shengjie; Zhang, Panpan; Han, Wenfeng; Li, Ying; Tang, Haodong*,  Persulfate activation boosted highly efficient photodegradation of norfloxacin catalyzed by Pt selectively loading LaOCl (001),  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS , 655, 130223,  DEC 20 2022;        6、Cheng, Zaizhe; Jiang, Chuan; Sun, Xiucheng; Lan, Guojun; Wang, Xiaolong; He, Lingjie; Li, Yunzhi; Tang, Haodong; Li, Ying,   Insights into the Inducing Effect of Aluminum on Cu-ZnO Synergy for Methanol Steam Reforming,  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,  61(32),  11699-11707,  AUG 17 2022;        7、Tang, Haodong; Zheng, Xiali; Yu, Yun; Liang, Jinxin; Zheng, Yifan; Liu, Zongjian     Undercooling, Thermal Stability, and Application in Exothermic Catalytic Reaction of SiO2 Encapsulated SnZnCu Microspheres，CATALYSTS, 12（2）, 205  FEB 2022;        8、Gao, Zhiyan; Huang, Zhiling; Meng, Yue; Tang, Haodong; Ni, Zheming; Xia, Shengjie    Theoretical study on the mechanism of CO2 adsorption and reduction by single-atom M (M = Cu, Co, Ni) doping C2N,    CHEMICAL PHYSICS LETTERS,  804, 139902,  OCT 2022;2021年1、Zhang Lei; Li Yu-Zhen; Li Li-Chun; Han Wen-Feng; Li Ying; Tang Hao-Dong*，Fe-Doped MgF2 Catalyst: Preparation by Sol-Gel Method and Performance in Dehydrogenation of 1,1-Difluoroalkane (R152a)，CHINESE JOURNAL OF INORGANIC CHEMISTRY，2021，（37）1，39-462、Tian, Youwen; Luo, Wei; Wang, Yedan; Yu, Yun; Huang, Wanzhen; Tang, Haodong; Zheng, Yifan; Liu, Zongjian，Ultrasound-assisted fast encapsulation of metal microparticles in SiO2 via an interface-confined sol-gel method，ULTRASONICS SONOCHEMISTRY，2021    73                 3、Tang, Haodong; Wang, Yao; Zhang, Wujian; Liu, Zongjian; Li, Lichun; Han, Wenfeng; Li, Ying       Catalytic activity of Ru supported on SmCeOx for ammonia decomposition: The effect of Sm doping       JOURNAL OF SOLID STATE CHEMISTRY，2021，295                  4、Han, Wenfeng; Yang, Hong; Wang, Linzhe; Liu, Bing; Wei, Xiaoli; Chen, Aimin; Song, Weiyu; Tang, Haodong; Li, Ying     Confined aluminum fluoride layers derived from the in situ etching of Ti3AlC2 as the robust catalyst for dehydrofluorination reaction，APPLIED SURFACE SCIENCE，2021，538            5、Yang, Hong; Wu, Sen; Chen, Zhengfei; Li, Lichun; Wang, Haili; Liu, Bing; Tang, Haodong; Li, Ying; Chen, Aimin; Han, Wenfeng       Catalytic Performance for the Conversion of Potent Fluorinated Greenhouse Gases by Aluminium Fluorides with Different Morphology，CATALYSIS LETTERS，2021，（151），7，2065-20746、Tang, Haodong; Zhang, Wujian; Meng, Yue; Xia, Shengjie，A direct Z-scheme heterojunction with boosted transportation of photogenerated charge carriers for highly efficient photodegradation of PFOA: Reaction kinetics and mechanism，APPLIED CATALYSIS B-ENVIRONMENTAL，2021，285                  7、Tang, Haodong; Zhang, Wujian; Meng, Yue; Xie, Bo; Ni, Zheming; Xia, Shengjie  Investigation onto the performance and mechanism of visible light photodegradation of methyl orange catalyzed by M/CeO2 (M=Pt, Ag, Au)，MATERIALS RESEARCH BULLETIN，2021，144   2020年1、Wang, Xiaolong; Lan, Guojun; Cheng, Zaizhe; Han, Wenfeng; Tang, Haodong; Liu, Huazhang; Li, Ying，Carbon-supported ruthenium catalysts prepared by a coordination strategy for acetylene hydrochlorination，CHINESE JOURNAL OF CATALYSIS，2020，（41），11，1683-1691        2、Liu, Bing; Han, Wenfeng; Chen, Aimin; Li, Lichun; Tang, Haodong; Lu, Chunshan; Zhang, Geshan; Li, Ying; Li, XiaonianConfinement of AlF 3 in MOF derived structures for the formation of 4-fold coordinated Al and significantly improved dehydrofluorination activity，CHEMICAL ENGINEERING JOURNAL，2020，394                 3、Han, Wenfeng; Wang, Haili; Liu, Bing; Li, Xiliang; Tang, Haodong; Li, Ying; Liu, Huazhang，PVDF mediated fabrication of freestanding AlF3 sub-microspheres: Facile and controllable synthesis of alpha, beta and theta-AlF3，MATERIALS CHEMISTRY AND PHYSICS，2020，240                        4、Yu, Wei; Han, Wenfeng; Liu, Yongnan; Lu, Jiaqin; Yang, Hong; Liu, Bing; Tang, Haodong; Chen, Aimin; Li, Ying，Facile Preparation of BaClxFy for the Catalytic Dehydrochlorination of 1-Chloro-1,1-Difluoroethane to Vinylidene Fluoride，CATALYSTS，      2020，10，4                     5、Chen, Zhengfei; Deng, Meng; Gao, Zhanghua; Jiang, Zhijiang; Li, Lichun; Tang, Haodong，Reaction evolution of a solvate fluoride ionic liquid induced fluorination process probed by Raman spectroscopy，JOURNAL OF MOLECULAR LIQUIDS，2020，305                        6、Ma, Yongcheng; Lan, Guojun; Fu, Wenzhao; Lai, Ying; Han, Wenfeng; Tang, Haodong; Liu, Huazhang; Li, Ying，Role of surface defects of carbon nanotubes on catalytic performance of barium promoted ruthenium catalyst for ammonia synthesis，JOURNAL OF ENERGY CHEMISTRY，2020，（41），  79-86       7、Zheng, Qifu; Wei, Xiaoli; Li, Xiliang; Liu, Bing; Chen, Aimin; Tang, Haodong; Han, Wenfeng   P-doped Carbon as the Efficient Support of Nickel Catalysts for Hydrodechlorination of Chlorodifluoromethane  ，CHEMISTRYSELECT，2020，（5），42，13290-13294       8、Zhang, Feiran; Wang, Wenjie; Li, Zhi; Kang, Yikun; Wang, Lu; Gao, Yang; Chen, Lulu; Zhang, Xiao; Song, Weiyu; Liu, Jian; Tang, Haodong，     The surface structure of beta-NiOOH (001) under reaction conditions and its effect on OER activity: An ab initio study，MOLECULAR CATALYSIS，2020，493                        9、Lan, Guojun; Ye, Qingfeng; Zhu, Yihan; Tang, Haodong; Han, Wenfeng; Li, Ying，Single-Site Au/Carbon Catalysts with Single-Atom and Au Nanoparticles for Acetylene Hydrochlorination，ACS APPLIED NANO MATERIALS，      2020（3），3，3004-3010       10、Lu, Jiaqin; Han, Wenfeng; Yu, Wei; Liu, Yongnan; Yang, Hong; Liu, Bing; Tang, Haodong; Li, Ying，Thermally conductive SiC as support of aluminum fluoride for the catalytic dehydrofluorination reaction，CATALYSIS COMMUNICATIONS，2020，142                          11、Tang, Haodong; Dang, MingMing; Zhang, Feiran; Xu, Bin; Zhang, Qing; Li, Lichun; Song, Weiyu; Han, Wenfeng; Li, Ying; Liu, Zongjian，The in situ redispersion of a PdCu/AC alloy catalyst under a CFCl2CF2Cl/H(2) atmosphere: a combination of experimental and DFT study，CHEMICAL COMMUNICATIONS，2020，（56），80，12001-120042019年及以前      1.        Yiyang Qiu,  Sajjad Ali, Guojun Lan, Huiqi Tong, Jiangtao Fan, Hongyang Liu, Bo Li, Wenfeng Han, Haodong Tang, Huazhang Liu, Ying Li. Defect-rich activated carbons as active and stable metal-free catalyst for acetylene hydrochlorination. Carbon, 2019, 146, 406-412      2.        Jinchao Wang, Wenfeng Han,* Shucheng Wang, Haodong Tang, Wucan Liu, Ying Li, Chunshan Lu,* Jianjun Zhang, Eric M. Kennedy and Xiaonian Li. Synergistic catalysis of carbon partitioned LaF3-BaF2 composite for the coupling of CH4 with CHF3 to VDF. Catalysis Science & Technology, 2019, 9(6): 1338–1348  DOI: 10.1039/C8CY02376J      3.           Haili Wang, Wenfeng Han*, Xiliang Li, Bing Liu, Haodong Tang, Ying Li. Solution combustion synthesis of Cr2O3 nanoparticles and the catalytic performance for dehydrofluorination of 1,1,1,3,3-pentafluoropropane to 1,3,3,3-tetrafluoropropene. Molecules, 2019, 24(2):361      4.        Jian Li a,†, Jiangtao Fan a,†, Sajjad Ali b, Guojun Lan a, Haodong Tang a, Wenfeng Han a, Huazhang Liu a, Bo Li b,#, Ying Li a,* The origin of the extraordinary stability of mercury catalysts on the carbon support: the synergy effects between oxygen groups and defects revealed from a combined experimental and DFT study, Chinses Journal of Catalysis, 2019      5.        GuoJun Lan,  Yiyang Qiu,  Jiangtao Fan,  Xiaolong Wang,  Haodong Tang,  Wenfeng Han,  Huazhang Liu,  Hongyang Liu,  Shuang SONG  and  Ying Li. Defective graphene@diamond hybrid nanocarbon material as effective and stable metal-free catalyst for acetylene hydrochlorination. Chemical Communications, 2019, DOI: 10.1039/C8CC09361J      6.           Wenfeng Han*, Lingyu Wang, Zhi Li, Haodong Tang, Ying Li , Chao Huo, Guojun Lan, Xiazhen Yang and Huazhang Liu*. γ-Fe2O3 as the Precursor of Iron Based Catalyst Prepared by Solid-state Reaction at Room Temperature for Fischer-Tropsch to Olefins. Applied Catalysis A, General, 2019, 572, 158-167 DOI: /10.1016/j.apcata.2019.01.002       7.           TANG Haodong*, XIANG Meng, XU Bin, LI Ying, HAN Wenfeng and LIU Zongjian*. One-step Synthesis of N-Doped Mesoporous Carbon as Highly Efficient Support of Pd Catalyst for Hydrodechlorination of 2,4-Dichlorophenol. Chem. Res. Chin. Univ., 2018, 34(6):1004-1008      8.           Zhikun Wang, Wenfeng Han*, Haodong Tang, Huazhang Liu. CaBaFx composite as robust catalyst for the pyrolysis of 1-chloro-1,1-difluoroethane to vinylidene fluoride. Catalysis Communications, 2019, 120:42-45      9.        Yaping Zhou, Yongcheng Ma, Guojun Lan, Haodong Tang, Wenfeng Han, Huazhang Liu, Ying Li. A highly stable and active mesoporous ruthenium catalyst for ammonia synthesis prepared by a RuCl3-SiO2‐templated approach.Chin. J. Catal., 2019, 40: 114–123.      10.       Wenfeng Han,* Jinchao Wang, Lulu Chen, Luteng Yang, Shucheng Wang, Miao Xi, Haodong Tang, Wucan Liu, Weiyu Song,* Jianjun Zhang, Ying Li, and Huazhang Liu. Reverting fluoroform back to chlorodifluoromethane and dichlorofluoromethane: Intermolecular Cl/F exchange with chloroform at moderate temperatures, Chemical Engineering Journal, 2019, 355,594-601      11.       Zhikun Wang, Wenfeng Han*, Haodong Tang, Ying Li, Huazhang Liu. Preparation of N-doped ordered mesoporous carbon and catalytic performance for the pyrolysis of 1-chloro-1,1-difluoroethane to vinylidene fluoride. Microporous & Mesoporous Materials, 2019, 275,200-206 育人成果

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