赵万祥

基本信息 赵万祥，湖南大学化学化工学院副院长，化学生物传感与计量学国家重点实验室教授、博士生导师，2017年入选第13批海外高层次人才计划。2014年博士毕业于香港科技大学，2014-2017先后在密歇根大学（安娜堡分校）John Montgomery教授课题组和犹他大学JACS主编Peter Stang教授课题组从事博士后，以通讯作者和第一作者在Nat. Chem., J. Am. Chem. Soc，Angew. Chem. Int. Ed 等期刊发表高水平论文40余篇。

教育背景

教育背景 2011.02-2014.02           博士研究生           香港科技大学（导师：孙建伟教授）2007.09-2010.07           硕士研究生           华东师范大学（导师：张俊良教授）

工作履历

工作履历 2017.03-至今               湖南大学化学化工学院2016.03-2017.03         犹他大学（博士后合作导师：Peter Stang）2014.02-2016.02         密歇根大学安娜堡分校（博士后合作导师：John Montgomery）

研究领域

研究领域 1：金属有机化学 2：有机合成方法学3：超分子化学

学术成果

学术成果   独立工作代表性论文： 15. Mixed Valence BN-Doped Corannulene Trimer Radical Cations Yapei Gao, Zheming Liu, Tao Li*, and Wanxiang Zhao*, Angew. Chem. Int. Ed. 2023, 62, e202314006 14. Cobalt-Catalyzed Asymmetric Remote Borylation of Alkyl Halides Minghao Zhang,# Zhiyang Ye,# and Wanxiang Zhao*, Angew. Chem. Int. Ed. 2023, 62, e202306248 13. Rhodium-Catalyzed Remote Borylation of Alkynes and Vinylboronates Minghao Zhang, Zheming Liu, and Wanxiang Zhao*, Angew. Chem. Int. Ed. 2023, 62, e202215455. 12. Asymmetric Oxidative Lactonization of Enynyl Boronates Kezhuo Zhang#, Chenchen Li#, Yining Jia, and Wanxiang Zhao*, Angew. Chem. Int. Ed. 2022, 61,  e202209004. 11. Enantioselective Cobalt-Catalyzed Hydroboration of Ketone-Derived Silyl Enol Ethers Wenke Dong, Zhiyang Ye, and Wanxiang Zhao*, Angew. Chem. Int. Ed. 2022, 61,  e2021174 10. Rhodium-Catalyzed Regioselective and Chemoselective Deoxygenative Reduction of 1,3-Diketones Bing Zhang,§ Xueying Guo,§ Lei Tao, Ruolin Li, Zhenyang Lin,* and Wanxiang Zhao*, ACS Catal. 2022, 12, 4640-4647. 9. Enantioselective Rh-Catalyzed Hydroboration of Silyl Enol Ethers Wenke Dong,# Xin Xu,# Honghui Ma, Yaqin Lei, Zhenyang Lin, and Wanxiang Zhao*, J. Am. Chem. Soc. 2021, 143, 10902-10909. 8. Rhodium-Catalyzed Regiodivergent Synthesis of Alkylboronates via Deoxygenative Hydroboration of Aryl Ketones: Mechanism and Origin of Selectivities Bing Zhang,§ Xin Xu,§ Lei Tao, Zhenyang Lin,* and Wanxiang Zhao*, ACS Catal. 2021, 11, 9495-9505. 7. Stereodefined tetraarylethylenes: Synthesis and applications Minghao Zhang and Wanxiang Zhao*, Aggregate. 2021;2:e60. 6. Rhodium-Catalyzed Deoxygenation and Borylation of Ketones: A Combined Experimental and Theoretical Investigation Lei Tao,∇ Xueying Guo,∇ Jie Li, Ruoling Li, Zhenyang Lin,* and Wanxiang Zhao*, J. Am. Chem. Soc. 2020, 142, 18118-18127. 5. Divergent and Stereoselective Synthesis of Tetraarylethylenes from Vinylboronates Minghao Zhang, Yisen Yao, Peter J. Stang* and Wanxiang Zhao*, Angew. Chem. Int. Ed. 2020, 59, 20090-20098. 4. Oxidation of Alkynyl Boronates to Carboxylic Acids, Esters and Amides Chenchen Li, Pei Zhao, Ruoling Li, Bing Zhang, and Wanxiang Zhao*, Angew. Chem. Int. Ed. 2020, 59, 10913-10917. 3. Rhodium‐Catalyzed Remote C(sp3)−H Borylation of Silyl Enol Ethers Jie Li, Shuanglin Qu, and Wanxiang Zhao*, Angew. Chem. Int. Ed. 2020, 59, 2360-2364.   2. Formation of a Supramolecular Polymeric Adhesive via Water-Participant Hydrogen Bonding Formation Qiao Zhang,⊥ Tao Li,⊥ Abing Duan,⊥ Shengyi Dong,* Wanxiang Zhao,* and Peter J. Stang*, J. Am. Chem. Soc. 2019, 141, 8058-8063. 1. Triflimide (HNTf2) in Organic Synthesis Wanxiang Zhao and Jianwei Sun*, Chem. Rev. 2018, 118, 10349-10392.        独立工作前代表性论文： 6. Zhao, W.; Montgomery, J.* Cascade Copper-Catalyzed 1,2,3-Trifunctionalization of Terminal Allenes J. Am. Chem. Soc. 2016, 138, 9763-9766. 5. Zhao, W.; Montgomery, J.* Functionalization of Styrenes via Copper-Catalyzed Borylation/ortho-Cyanation and Silver-Catalyzed Annulation Processes Angew. Chem. Int. Ed. 2015, 54, 12683-12683. 4. Zhao, W.; Wang, Z.; Chu, B.; Sun, J*. Enantioselective Formation of All-Carbon Quaternary Stereocenters from Indoles and Tertiary Alcohols Bearing A Directing Group Angew. Chem. Int. Ed. 2015, 54, 1910-1913 (Highlighted in SynFact) 3. Zhao, W.; Qian, H.; Li, Z*.; Sun, J.* Catalytic Ring Expansion of Cyclic Hemiaminals for the Synthesis of Medium Ring Lactams Angew. Chem. Int. Ed. 2015, 54, 10005-10008. 2. Zhao, W.; Li, Z.; Sun, J*. A New Strategy for Efficient Synthesis of Medium and Large Ring Lactones without High Dilution or Slow Addition J. Am. Chem. Soc. 2013, 135, 4680-4683. 1. Zhao, W.; Wang, Z.; Sun, J*. Synthesis of 8-Membered Lactones via Intermolecular [6+2] Cyclization of New Amphoteric Molecules with Siloxy Alkynes. Angew. Chem. Int. Ed. 2012, 51, 6209-6213.