许新华

基本信息 男，1964年11月出生，博士，教授，博士生导师。 1991年获湖南师范大学有机化学硕士学位；1998年获杭州大学有机化学专业博士学位，从事有机合成方法和金属有机化学研究，师从黄宪院士；1998.6-2000.6在南开大学元素有机国家重点实验室进行药物化学博士后研，合作老师为陈茹玉院士；2000年6月至今在湖南大学化学化工学院工作；2002年度在日本Okayama 大学进行博士后研究。近几年主持国家自然科学基金和部省级科研项目10余项；作为通信联系人在国际重要刊物J. Org. Chem., Org. Lett., Adv. Synth. Catal. Green Chem.,Chem.Commun.等权威刊物及SCI原刊发表论文120余篇，申请发明专利41项。培养硕士生80余名，博士生10名。

教育背景

教育背景 1981.9-1984.6，湖南邵阳师范专科学校化学科学习。1988.9-1991.6，湖南师范大学化学系有机专业硕士生，指导老师:俞善信教授。1995.9-1998.6，杭州大学化学系有机化学专业博士生，指导老师：黄宪院士。1998.9-2000.6，南开大学元素所药物化学专业博士后，合作老师：陈茹玉院士。2002年度在日本冈山理工大学应用研究所从事超分子研究。

工作履历

工作履历 1984.6-1988.8，湖南武冈泉塘乡中学、武冈湾头桥区中学担任初中、高中化学教学。1991.6-1995.8，湖南农学院基础部担任本科《有机化学》理论、实验教学。2000.6-至今， 湖南大学化工学院担任本科《有机化学》理论、实验教学；担任硕士生《金属有机》、《元素有机》、《超分子化学》教学。

研究领域

科研项目 1、国家自然科学基金面上项目：对水稳定的金属Lewis acid研制与应用研究， 2004.1-2006.12。2、国家自然科学基金面上项目：对空气稳定的新颖的有机金属Lewis acid制备、表征及应用研究， 2012.1-2013.12。3、国家自然科学基金面上项目：新型有机铯配合物合成、表征及其在碳-杂键形成反应中的催化应用研究， 2013.1-2016.12。4、国家自然科学基金重点项目：“化学溶剂吸收法捕获二氧化碳过程降低热能消耗关键科学问题研究”子课题“新型有机胺合成研究”负责人， 2016.1-2020.12 5、湖南省重大科技专项：“4- ADl绿色生物合成与甾体类药物研发”子课题“度他雄胺原料药注册申报及原料药产业化研究”负责人，2014.6-2017.6。

学术成果

学术成果 近5年发表论文：[1] Linghui Lu, Sijia Zhou, Meng Sun, Jialiang Chen, Wen Xia, Xianyong Yu, Xinhua Xu*, and Wei-Min He*, Metal- and Solvent-Free Ultrasonic Multicomponent Synthesis of (Z)-β-Iodo Vinylthiocyanates, ACS Sustainable Chem. Eng., 7 (1), 1574–1579, 2019.(IF=6.140)[2] Yanxia Nan, Wenjie Zhao*, Ningbo Li, Zhiwu Liang*, Xinhua Xu*, Chemiluminescence-triggered fluorophore release: Approach for in vivo fluorescence imaging of hydrogen peroxide, Sensors & Actuators: B. Chemical., 281, 296–302, 2019.(IF=5.667)[3] Zheng‐Jun Wang , Jing‐Jing Lv, Rong‐Nan Yi, Min Xiao, Jiu‐Ju Feng, Zhi‐Wu Liang*,  Ai‐Jun Wang*, Xinhua Xu*, Nondirecting Group sp3 C−H Activation for Synthesis of Bibenzyls via Homo‐coupling as Catalyzed by Reduced Graphene Oxide Supported PtPd@Pt Porous Nanospheres, Adv. Synth. Catal., 360, 932–941, 2018.(IF=5.123)[4] Ningbo Li, Lingxiao Wang, Liting Zhang, Wenjie Zhao, Jie Qiao, Xinhua Xu*, Zhiwu Liang, Air‐stable Bis(pentamethylcyclopentadienyl) Zirconium Perfluorooctanesulfonate as an Efficient and Recyclable Catalyst for the Synthesis of N‐substituted Amides, Chem.Cat.Chem., 10, 3532, 2018.(IF=4.674)[5] Ling-Hui Lu, Si-Jia Zhou,  Wei-Bao He,  Wen Xia,  Ping Chen,  Xianyong Yu,  Xinhua Xu*  and  Wei-Min He*, Metal-free difunctionalization of alkynes leading to alkenyl dithiocyanates and alkenyl diselenocyanates at room temperature, Org. Biomol. Chem., 16, 9064, 2018.(IF=3.423)[6] Rongnan Yi, Jinyang Chen, Xueyan Wang, Zhiwu Liang*, Xinhua Xu*,A Rapid and Highly Efficient Method for the Synthesis of Benzofulvenes via CsOH‐Catalyzed Condensation of Indene and Aldehydes, Eur.J.Org.Chem., 11, 1347–1351, 2018.(IF=2.882)[7] Ningbo Li, Lingxiao Wang, Haojiang Wang, Jie Qiao, Zhiwu Liang, Wenjie Zhao*, Xinhua Xu*, Synthesis and structure of an air-stable bis(pentamethylcyclopentadienyl) zirconium pentafluorbezenesulfonate and its application in catalytic epoxide ring-opening reactions, Tetrahedron, 74, 1033-1039, 2018.(IF=2.377)[8] Xiaohong Zhang, Xinhua Xu*, Ningbo Li, Zhiwu Liang*, Zilong Tang, Air-stable μ2-hydroxyl bridged cationic binuclear complexes of zirconocene perfluorooctanesulfonates: their structures, characterization and application, Tetrahedron, 74, 1926-1932, 2018.(IF=2.377)[9] Ningbo Li, Jiao Yao, Lingxiao Wang, Jiancong Wei*, Wen Liu, Wenqi Liu*, Xinhua Xu*, Zhiwu Liang,Titanocene perfluorobutanesulfonate catalyzed reduction of disulfides in the presence of zinc to synthesize unsymmetrical sulfides, Inorganic Chemistry Communication., 98, 99−104, 2018.(IF=1.810)[10]  Zhi Tang, Qiutao Jiang, Lifen Peng, Xinhua Xu*, Jie Li*, Renhua Qiu* and Chak-Tong Au, Zirconocene-catalyzed direct (trans)esterification of acyl acids (esters) and alcohols in a strict 1 : 1 ratio under solvent-free conditions, Green Chem., 19, 5396–5402, 2017. (IF= 9.125)[11] Zheng-Jun Wang, Xue-Yan Wang, Xia Wanga, Zhi-Wu Liang, Xinhua Xu*, Carbonylative Suzuki cross-coupling reaction catalyzed by bimetallic Pd-Pt nanodendrites under ambient CO pressure, Catal. Commun., 101, 10-14, 2017. (IF= 3.33) [12] Zheng-Jun Wang, Xia Wang, Jing-Jing Lv, Jiu-Ju Feng, Xinhua Xu*, Ai-Jun Wang* and Zhiwu Liang, Bimetallic Au–Pd nanochain networks: facile synthesis and promising application in biaryl synthesis, New J. Chem., 41, 3894, 2017. (IF= 3.269）[13] Lifen Peng, Rongzhen Li, Zilong Tang*, Jingyang Chen, Rongnan Yi, Xinhua Xu*, Cesium-catalyzed highly regioselective synthesis of (Z)-vinylic selenosulfides via thioselenation of alkynes with unsymmetrical diorganoyl dichalcogenides, Tetrahedron., 73, 3099-3105, 2017. (IF= 2.651)[14] 毛冀川, 申玉良, 曹春雨, 舒志坚, 郑良彬, 许新华*, 利用过二硫酸盐氧化消除 2-碘双氢非那雄胺制备非那雄胺[J]. 有机化学, 2017, 37, 2430-2434.[15] 陈锦杨, 吴小波, 易荣楠, 许新华*, 镍催化格氏试剂与二芳基乙炔偶联反应制备四取代萘[J]. 有机化学, 2017, 37, 1850-1854.[16] Jinyang Chen, Sihai Chen, Xinhua Xu*, Zhi Tang, Chak-Tong Au, and Renhua Qiu*, Nickel-Catalyzed Regioselective Cleavage of Csp2−S Bonds: Method for the Synthesis of Tri- and Tetrasubstituted Alkenes, J. Org. Chem., 81, 3246−3255, 2016. (IF= 4.849)[17] Jing-Jing Lv, Zheng-Jun Wang, Jiu-Ju Feng, Renhua Qiu*, Ai-Jun Wanga*, Xinhua Xu*, Facile synthesis of highly active Pd-Cu nanowires catalyst through a simple wet-chemical strategy for ligand-free Suzuki cross coupling reaction, Applied Catalysis A: General., 522, 188-193, 2016. (IF= 4.339)[18] Penghui Wang, Jinying Wang, Chak-Tong Au, Renhua Qiu*, Xinhua Xu*, Shuang-Feng Yin*, Air-stable organobismuth(V) bisperfluorooctanesulfonate as an efficient catalyst for the synthesis of N-containing compounds, Adv. Synth. Catal., 358, 1302-1308, 2016. (IF= 5.646) [19] Sihai Chen, You Li, Jinyang Chen, Xinhua Xu*, Lebin Su, Zhi Tang, Chak-Tong Au, Renhua Qiu*, Iodine-Promoted Synthesis of Thioamides from 1,2-Dibenzylsulfane and Difurfuryl Disulfide, Synlett., 27(16), 2339-2344, 2016. (IF= 2.151)[20] Sihai Chen, Jinyang Chen, Xinhua Xu*, Yunhua He, Rongnan Yi, Renhua Qiu*, Calix[4]arene-assisted KOH-catalyzed synthesis of O,O-dialkyl-Se-aryl phosphoroselenoates, J. Org. Chem., 818, 123-127, 2016. (IF= 2.184)[21] Xie Wang, Longzhi Zhu, Sihai Chen, Xinhua Xu,* Chak-Tong Au, and Renhua Qiu*, Nickel-Catalyzed Direct C (sp3)−H Arylation of Aliphatic Amides with Thiophenes, Org. Lett., 17, 5228−5231, 2015. (IF= 6.579)[22] Xie Wang, Renhua Qiu,* Chunyang Yan, Vutukuri Prakash Reddy, Longzhi Zhu, Xinhua Xu,* and Shuang-Feng Yin*, Nickel-Catalyzed Direct Thiolation of C(sp3)−H Bonds in Aliphatic Amides, Org. Lett., 17, 1970-1973, 2015. (IF= 6.579)[23] Jinyang Chen, Zhi Tang, Renhua Qiu,* Yunhua He, Xie Wang, Ningbo Li, Haibo Yi,* Chak-Tong Au, Shuang-Feng Yin, and Xinhua Xu*, Cesium-Catalyzed Regioselective Synthesis of Trisubstituted Heteroatom Alkenes: A New Strategy for the Preparation of Functional Alkenes, Org. Lett., 17, 2162−2165, 2015. (IF= 6.579)[24] Xiaohong Zhang, Renhua Qiu*, Congcong Zhou, Jingxing Yu, Ningbo Li, Shuangfeng Yin*, Xinhua Xu*, Synthesis and structure of an air-stable bis(isopropylcyclopentadienyl) zirconium perfluorooctanesulfonate and its catalyzed benzylation of 1,3-dicarbonyl derivatives with alcohols, Tetrahedron., 71, 1011-1017, 2015. (IF= 2.651)[25] Ningbo Li, Renhua Qiu*, Xiaohong Zhang, Yun Chen, Shuang-Feng Yin*, Xinhua Xu*, Strong Lewis acids of air-stable binuclear triphenylantimony(V) complexes and their catalytic application in CeC bond-forming reactions, Tetrahedron., 71, 4275-4281, 2015. (IF= 2.651)[26] Jinying Wang, Ningbo Li, Renhua Qiu*, Xiaohong Zhang, Xinhua Xu*,Shuang-Feng Yin*, Air-stable zirconocene bis(perfluorobutanesulfonate) as a highly efficient catalyst for synthesis of N-heterocyclic compounds, J. Org. Chem., 785, 61-67, 2015. (IF= 2.184)[27] Qizhi Dong, Ningbo Li, Renhua Qiu*, Jinying Wang, Cancheng Guo*, Xinhua Xu*, Silver-containing microemulsion as a high-efficient and recyclable catalytic system for hydration of alkynes, J. Org. Chem., 799-800, 122-127, 2015. (IF= 2.184)[28] Zheng-Jun Wang, Jing-Jing Lv, Jiu-Ju Feng, Ningbo Li, Xinhua Xu*, Ai-Jun Wang* and Renhua Qiu*, Enhanced catalytic performance of Pd–Pt nanodendrites for ligand-free Suzuki crosscoupling reactions, RSC Adv., 5, 28467–28473, 2015. (IF= 3.108)[29] Zheng-Jun Wang, Peng-Hui Wang, Jing-Jing Lv, Jiu-Ju Feng, Xinhua Xu,* Ai-Jun Wang,* Chak-Tong Au and Renhua Qiu*, Cu(II)@Luviset clear as recyclable catalyst for the formation of C–C bond in homo-coupling of terminal alkynes, RSC Adv., 5, 96372–96376, 2015. (IF= 3.108)[30] Yanxia Nan, Wenjie Zhao, Xinhua Xu,* Chak-Tong Au and Renhua Qiu*, Synthesis, characterization and applications of selenocysteine-responsive nanoprobe based on dinitrobenzene sulfonyl-modified poly(carbonate) micelles, RSC Adv., 5, 69299–69306, 2015. (IF= 3.108)[31] You Li, Jinyang Chen, Renhua Qiu*, Xie Wang, Jinguo Long, Longzhi Zhu, Chak-Tong Au, Xinhua Xu*, Cesium hydroxide-catalyzed isomerization of terminal alkynes for the synthesis of O-allenes and N-allenes, Tetrahedron Lett., 56, 5504–5507, 2015. (IF= 2.193)部分发明专利[1] 许世镗，许新华，陈锦杨，邱仁华，散煤燃烧废气与机动车废气净化装置及污染物资源化方法，ZL 201610905643.X[2] 梁志武，王雪艳，许新华，肖珉，一种合成炔丙胺类化合物的新方法，ZL 201711095532.8[3] 梁志武，王正军，许新华，肖珉，石墨烯负载钯/铂催化spC-H键偶联合成1,2-二苯乙烷衍生物的方法，ZL 201711095556.3[4] 梁志武，王正军，许新华，肖珉，一种通过sp3C-H键活化合成丙咪嗪前驱体2,2-二溴联苄的新方法，ZL 201711095713.0[5] 许新华，张秋林，李言杰，陈雄，张青丽，含硒替加氟的内盐式硫代磷酸酯类化合物及其合成，ZL 200410047110.X[6] 许新华，张秋林，周冰，甘油骨架上含硒的替加氟的硫代磷脂类化合物及其合成，ZL200410046925.6[7] 许新华， 刘凤伟， 齐建勇，臧中林， 李言杰，碳酸铯催化、乙腈为溶剂烷基芳醚的制备，ZL 200610031357.1[8] 许新华，度他雄胺及其中间体双键形成新方法，ZL 201710232764.7[9]