沈海民

个人简介 沈海民，男，中山大学工学博士，教授，硕士生导师，博士生导师，1983年04月出生于河北省张家口市蔚县。长期从事精细化工，绿色化学，仿生催化，催化氧化，催化还原研究。主持完成国家自然科学基金青年基金项目1项，主持国家自然科学基金面上项目2项，参与承担国家自然科学基金青年基金项目1项，参与承担国家自然科学基金面上项目1项。主持企业横向课题4项。在Chemical Engineering Journal、Chemical Engineering Science、Applied Catalysis A, General、Applied Surface Science、RSC Advances、New Journal of Chemistry、Catalysis Communications、Molecular Catalysis等国内外学术期刊上发表学术论文40余篇，申请中国发明专利40余件，授权中国发明专利11件，授权美国发明专利1件。主讲本科生专业必修课程绿色化工技术，化工安全与环境。浙江工业大学优秀班主任。浙江工业大学优秀教师。浙江工业大学优秀本科毕业论文指导教师。指导研究生获国家奖学金3人次，指导研究生获浙江工业大学一等学业奖学金15人次以上。学习经历：2002.09-2006.06，浙江工业大学，化学工程学院，化学工程与工艺专业，精细化工模块，获工学学士学位2006.09-2009.06，浙江工业大学，化学工程学院，应用化学专业，精细有机合成方向，获工学硕士学位(保送)，师从史鸿鑫教授2009.09-2012.06，中山大学，化学与化学工程学院，材料物理与化学专业，环境友好的化工过程及仿生催化方向，获工学博士学位，师从纪红兵教授 工作经历：2012.10-2016.12，浙江工业大学，化学工程学院，讲师，佘远斌教授团队2016.12-2018.12，浙江工业大学，化学工程学院，副教授，硕士生导师，佘远斌教授团队2019.01-2023.12，浙江工业大学，化学工程学院，副教授，硕士生导师，博士生导师，佘远斌教授团队2023年12月至今，浙江工业大学，化学工程学院，教授，硕士生导师，博士生导师，佘远斌教授团队 主持项目：1.  环糊精-Fe3O4超分子仿生催化体系的构筑及其对水相不对称反应的调控，国家自然科学基金青年基金项目，2013.01.01-2016.12.31，主持2.  双金属卟啉协同催化氧气选择性氧化环烷烃合成醇、酮研究，国家自然科学基金面上项目，2019.01.01-2022.12.31，主持3.  限域环境中双金属中心接力催化O2选择氧化烃类C-H键规律的研究，国家自然科学基金面上项目，2022.01.01- 2025.12.31，主持4.  一种防晒剂A二钠盐合成工艺的开发，企业横向课题，75.0万，主持5.  无水家用机洗洗衣液配方的研究和开发，企业横向课题，5.0万，主持6.  关键医药中间体的工艺研发，企业横向课题，100.0万，主持7.  电化铝烫印箔水溶性色料配方开发和涂布工艺改进，企业横向课题，10.0万，主持 主要学术论文：[39] Yuan-Bin She, Yu Zhang, Jia-Ye Ni, Xin-Yan Zhou, Hong-Liang Ye, Hai-Min Shen*. Practical and efficient oxygenation of benzylic C-H bonds with dioxygen catalyzed by two-dimensional porous organic frameworks possessing porphyrin cobalt(II) units [J]. Chemical Engineering Science, 2024, 293: 120056.[38] Yu Zhang, Bo Fu, Jing Sun, Yan-Bo Ding, Hai-Min Shen*, Yuan-Bin She*. Relay catalysis on the surface of hybrid silica functionalized with dual metalloporphyrins(Co&Zn) for efficient and selective oxygenation of cycloalkanes using oxygen [J]. Molecular Catalysis, 2024, 557: 113957.[37] Xin-Yan Zhou, Bo Fu, Wen-Dong Jin, Xiong Wang, Ke-Ke Wang , Mei Wang, Yuan-Bin She, Hai-Min Shen*. Efficient and Selective Oxygenation of Cycloalkanes and Alkyl Aromatics with Oxygen through Synergistic Catalysis of Bimetallic Active Centers in Two-Dimensional Metal-Organic Frameworks Based on Metalloporphyrins [J]. Biomimetics, 2023, 8(3): 325.[36] Jia-Ye Ni, Bin He, Hao Huang, Lei Ning, Qiu-Ping Liu, Ke-Ke Wang, Hong-Ke Wu, Hai-Min Shen*, Yuan-Bin She*. Cycloalkanes oxidation with O2 in high-efficiency and high-selectivity catalyzed by 3D MOFs with limiting domain and Zn(AcO)2 through synergistic mode [J]. Molecular Catalysis, 2023, 540: 113027.[35] Xin-Yan Zhou, Bin He, Yu Zhang, Jia-Ye Ni, Qiu-Ping Liu, Mei Wang, Hai-Min Shen*, Yuan-Bin She*. Selective and Efficient Catalytic Oxygenation of Alkyl Aromatics Employing H2O2 Catalyzed by Simple Porphyrin Iron(II) under Mild Conditions [J]. Processes, 2023, 11: 1187.[34] Hai-Min Shen, Hong-Liang Ye, Jia-Ye Ni, Ke-Ke Wang, Xin-Yan Zhou, Yuan-Bin She*. Oxidation of α-C-H bonds in alkyl aromatics with O2 catalyzed by highly dispersed cobalt(II) coordinated in confined reaction channel of porphyrin-based POFs with simultaneously enhanced conversion and selectivity [J]. Chemical Engineering Science, 2023, 270: 118472.[33] A-Bing Guo, Jia-Wei Qin, Ke-Ke Wang, Qiu-Ping Liu, Hong-Ke Wu, Mei Wang, Hai-Min Shen*, Yuan-Bin She. Synergetic catalytic oxidation of C-H bonds in cycloalkanes and alkyl aromatics by dimetallic active sites in 3D metalloporphyrinic MOFs employing O2 as oxidant with increased conversion and unconsumed selectivity [J]. Molecular Catalysis, 2023, 535:112853.[32] Hai-Min Shen, Xiong Wang, Hao Huang, Qiu-Ping Liu, Dong Lv, Yuan-Bin She*. Staged oxidation of hydrocarbons with simultaneously enhanced conversion and selectivity employing O2 as oxygen source catalyzed by 2D metalloporphyrin-based MOFs possessing bimetallic active centers [J]. Chemical Engineering Journal, 2022, 443: 136126.[31] Hai-Min Shen, A-Bing Guo, Yu Zhang, Qiu-Ping Liu, Jia-Wei Qin, Yuan-Bin She*. Relay catalysis of hydrocarbon oxidation using O2 in the confining domain of 3D metalloporphyrin-based metal-organic frameworks with bimetallic catalytic centers [J]. Chemical Engineering Science, 2022, 260: 117825.[30] Jia-Ye Ni, Shu-Zhen Cong, Lei Ning, Mei Wang, Hai-Min Shen*, Yuan-Bin She*. Binary catalytic systems constructed by porphyrin cobalts(II) with confining nano-region and Zn(OAc)2 for oxygenation of cycloalkanes with O2 in relay mode [J]. Molecular Catalysis, 2022, 531:112676.[29] Hai-Min Shen, Xiong Wang, Lei Ning, A-Bing Guo, Jin-Hui Deng, Yuan-Bin She*. Efficient        oxidation of cycloalkanes with simultaneously increased conversion and selectivity using O2 catalyzed by metalloporphyrins and boosted by Zn(AcO)2: A practical strategy to inhibit the formation of aliphatic diacids [J]. Applied Catalysis A, General, 2021, 609: 117904.[28] Hai-Min Shen, Hong-Liang Ye, Qin Wang, Meng-Yun Hu, Lei Liu, Yuan-Bing She*. Efficient oxidation of cumene to cumene hydroperoxide with ambient O2 catalyzed by metalloporphyrins [J]. Journal of Porphyrins and Phthalocyanines, 2021, 25: 314-322.[27] Hai-Min Shen, Meng-Yun Hu, Lei Liu, Bei Qi, Hong-Liang Ye, Yuan-Bin She*. Efficient and selective oxidation of tertiary benzylic C-H bonds with O2 catalyzed by metalloporphyrins under mild and solvent-free conditions [J]. Applied Catalysis A, General, 2020, 599: 117599.[26] Hai-Min Shen, Bei Qi, Meng‑Yun Hu, Lei Liu, Hong‑Liang Ye, Yuan‑Bin She*. Selective Solvent-Free and Additive-Free Oxidation of Primary Benzylic C-H Bonds with O2 Catalyzed by the Combination of Metalloporphyrin with N‑Hydroxyphthalimide [J]. Catalysis Letters, 2020, 150: 3096-3111.[25] Hai-Min Shen*, Lei Liu, Bei Qi, Meng-Yun Hu, Hong-Liang Ye, Yuan-Bin She. Efficient and selective oxidation of secondary benzylic C-H bonds to ketones with O2 catalyzed by metalloporphyrins under solvent-free and additive-free conditions [J]. Molecular Catalysis, 2020, 493: 111102.[24] Hai-Min Shen, Xiong Wang, A-Bing Guo, Long Zhang, Yuan-Bing She*. Catalytic oxidation of cycloalkanes by porphyrin cobalt(II) through efficient utilization of oxidation intermediates [J]. Journal of Porphyrins and Phthalocyanines, 2020, 24: 1166-1173.[23] Hai-Min Shen, Long Zhang, Jin-Hui Deng, Jing Sun, Yuan-Bin She*. Enhanced catalytic performance of porphyrin cobalt(II) in the solvent-free oxidation of cycloalkanes (C5~C8) with molecular oxygen promoted by porphyrin zinc(II) [J]. Catalysis Communications, 2019, 132: 105809 .[22] Hai-Min Shen, Yan Wang, Jin-Hui Deng, Long Zhang, Yuan-Bin She*. Catalyst-free and solvent-free oxidation of cycloalkanes (C5-C8) with molecular oxygen: Determination of autoxidation temperature and product distribution[J]. Chinese Journal of Chemical Engineerin，2018，26(5)：1064-1070.[21] 佘远斌，邓金辉，张龙，沈海民*. 氧气催化氧化环己烷[J].化学进展，2018，30(1)：124-136.[20] 沈海民，王岩，佘远斌*.金属卟啉催化氧化环己烷最新研究进展[J].化工进展，2018，37(6)：2031-2045.[19] 韩叶强，周文杰，沈海民*，刘秋平，于文艳，纪红兵，佘远斌*.固载化β-环糊精吸附环境污染物的研究进展[J].有机化学，2016，36(2)：248-257.[18] Hai-Min Shen*，Wen-Jie Zhou，Wu-Bin Yu，Hong-Ke Wu，Qiu-Ping Liu，Hong-Bing Ji，Yan Wang，Yuan-Bin She*.Metal-free chemoselective oxidation of sulfides to sulfoxides catalyzed by immobilized L-aspartic acid and L-glutamic acid in an aqueous phase at room temperature[J].New Journal of Chemistry，2016，40(6)：4874-4878.[17] 沈海民*，武宏科，史鸿鑫，纪红兵，余武斌*.非均相环糊精在水相有机合成反应中的应用[J].化学进展，2015，27(1)：70-78.[16] 沈海民*，方红果，武宏科，纪红兵，史鸿鑫*.环糊精衍生物的分子形态及其构筑策略研究进展[J].化工进展，2015，34(2)：430-446.[15] Hai-Min Shen*，Wen-Jie Zhou，Hong-Ke Wu，Wu-Bin Yu，Ning Ai，Hong-Bing Ji，Hong-Xin Shi，Yuan-Bin She*.Metal-free chemoselective oxidation of sulfides to sulfoxides catalyzed by immobilized taurine and homotaurine in aqueous phase at room temperature[J].Tetrahedron Letters，2015，56(30)：4494-4498.[14] Hai-Min Shen*，Wen-Jie Zhou，Xin Ma，Hong-Ke Wu，Wu-Bin Yu，Ning Ai，Hong-Bing Ji，Hong-Xin Shi， Yuan-Bin She*.pH-Dependence of the Aqueous Phase Room Temperature Brønsted Acid-Catalyzed Chemoselective Oxidation of Sulfides with H2O2[J].Molecules，2015，20(9)：16709-16722.[13] Hai-Min Shen，Gong-Yuan Zhu，Wu-Bin Yu，Hong-Ke Wu，Hong-Bing Ji，   Hong-Xin Shi，Yi-Fan Zheng*，Yuan-Bin She*.Surface immobilization of β-cyclodextrin on hybrid silica and its fast adsorption performance of p-nitrophenol from the aqueous phase[J].RSC Advances，2015，5(103)：84410-84422. [12] Hai-Min Shen*，Gong-Yuan Zhu，Wu-Bin Yu，Hong-Ke Wu，Hong-Bing Ji，Hong-Xin Shia，Yuan-Bin She，Yi-Fan Zheng.Fast adsorption of p-nitrophenol from aqueous solution using β-cyclodextrin grafted silica gel[J].Applied Surface Science，2015，356：1155-1167.[11] 沈海民*，武宏科，纪红兵，史鸿鑫*. β-环糊精-Fe3O4超分子体系的构筑及其应用研究进展[J].有机化学，2014，34(4)：630-646.[10] 沈海民*，纪红兵，武宏科，史鸿鑫*.β-环糊精的固载及其应用最新研究进展[J].有机化学，2014，34(8)：1549-1572.[9] Hai-Min Shen，Hong-Bing Ji*. Cyclodextrine-[RuCl2(Arene)]2 conjugates: another  way to enhancethe enantioselectivity of aromatic ketones reduction by aromatic ligands’ volume[J].Tetrahedron，2013，69(39)：8360-8367.[8] Hai-Min Shen，Hong-Bing Ji*.Amino alcohol-modified β-cyclodextrin inducing biomimetic asymmetric oxidation of thioanisole in water[J].Carbohydrate Research，2012，354：49-58.[7] 沈海民，纪红兵*.环糊精衍生物在金属催化有机合成中的应用[J].有机化学，2012，32(6)：975-985.[6] Hai-Min Shen，Hong-Bing Ji*.Biomimetic asymmetric aldol reactions catalyzed by proline derivatives attached to β-cyclodextrin in water[J].Tetrahedron Letters，2012，53(28)：3541-3545.[5] 沈海民，纪红兵*. β-环糊精衍生物诱导Na2MoO4催化H2O2不对称氧化苯甲硫醚[J].有机化学，2012，32(9)：1684-1689.[4] 沈海民，纪红兵*.环糊精衍生物在液相有机合成中的应用[J].有机化学，2011，31(6)：791-803.[3] 沈海民，史鸿鑫*，武宏科，项菊萍，朱春凤.N-(p-全氟壬烯氧基苯磺酰基)肌氨酸钠的合成与表面活性[J]. 高校化学工程学报，2009，23(4)：679-683.[2] 沈海民，史鸿鑫*，项菊萍，刘秋平，朱春凤.硫酸酯型氟表面活性剂的合成与表面活性[J].应用化学，2009，26(9)：1036-1039.[1] 沈海民，史鸿鑫*，武宏科，项菊萍.对全氟壬烯氧基苯磺酸钠的合成与表面活性[J].农药，2007，46(8)：520-522.授权专利：[12] 沈海民，张羽，孙静. 一种双金属中心金属卟啉及其制备方法和应用[P]. 申请号：202010884408.5, 申请日：2020.08.28. 申请公布号：CN112090449A, 申请公布日：2020.12.18. 授权公告号：CN112090449B，专利号：ZL 202010884408.5，授权公告日：2023.03.31. 申请人：浙江工业大学.[11] 沈海民，黄浩. 一种三金属中心(Co&Cu&Zn)2DMOFs/紫外光催化氧化环烷烃的方法[P]. 申请号：202111006432.X, 申请日：2021.08.30. 申请公布号：CN113603564A, 申请公布日：2021.11.05. 授权公告号：CN113603564B，专利号：ZL 202111006432.X，授权公告日：2023.03.14. 申请人：浙江工业大学.[10] 沈海民，黄浩. 一种金属卟啉三金属中心2DMOFs及其制备方法和应用[P]. 申请号：202111008838.1, 申请日：2021.08.31. 申请公布号：CN113683619A, 申请公布日：2021.11.23. 授权公告号：CN113683619B，专利号：ZL 202111008838.1,授权公告日：2023.07.14. 申请人：浙江工业大学.[9] Hai-Min Shen, Lei Ning, Yuan-Bin She. Confined Porphyrin Co(II) and Preparation Method and Application Thereof [P].  Patent No.: US11420991(B2), Date of Patent: 2022-08-23. Applicant: Zhejiang University of Technology.[8]  沈海民，任文山. 一种Cu(II)/硝酸二元催化体系催化O2氧化环己烯一步合成己二酸的方法[P]. 申请号：2021109811098, 申请日：2021.08.25. 申请公布号：CN113563176A, 申请公布日：2021.10.29. 专利号：ZL 2021109811098，授权公告号：CN113563176B，授权公告日：2022.12.20. 申请人：浙江工业大学.[7]  沈海民，丛淑贞. 封端3D钴(II)卟啉POF材料及其制备方法和应用[P]. 申请号：2021109875009, 申请日：2021.08.26. 申请公布号：CN113717394A, 申请公布日：2021.11.30. 专利号: 2021109875009. 授权公告号：CN113717394B，授权公告日：2022.06.03. 申请人：浙江工业大学.[6]  沈海民，宁磊，佘远斌. 一种限域性卟啉Co(II)及其制备方法和应用[P]. 申请号：2019111619249, 申请日：2019.11.25. 申请公布号：CN110938078A, 申请公布日：2020.03.31. 专利号: 2019111619249. 授权公告号：CN110938078B，授权公告日：2021.01.01. 申请人：浙江工业大学.[5]  沈海民，齐备，佘远斌. 甲苯类化合物选择性氧化的方法[P]. 申请号：2019108011331, 申请日：2019.08.28. 申请公布号：CN110563590A, 申请公布日：2019.12.13. 专利号: 2019108011331. 授权公告号：CN110563590B，授权公告日：2022.03.18. 申请人：浙江工业大学.[4]  沈海民, 叶宏亮, 佘远斌. 一种乙苯及其衍生物选择性氧化制备苯乙酮及其衍生物的方法[P]. 申请号：2019107949087, 申请日：2019.08.27. 申请公布号：CN110498745A, 申请公布日：2019.11.26. 专利号: 2019107949087. 授权公告号：CN110498745B，授权公告日：2022.06.17. 申请人：浙江工业大学.[3]  沈海民, 史鸿鑫, 武宏科. 一种不锈钢氧化层清洗剂及其制备方法和应用[P]. 申请号：2014100424102, 申请日：2014.01.28. 申请公布号：CN103820797A, 申请公布日: 2014.05.28. 申请人：浙江工业大学. 授权专利号: 2014100424102, 授权公告号: CN103820797B, 授权日: 2016.05.18.[2]  佘远斌, 刘磊, 沈海民. 一种乙苯类化合物选择性氧化的方法[P]. 申请号：2019108011346, 申请日：2019.08.28. 申请公布号：CN110483222A, 申请公布日：2019.11.22. 专利号: 2019108011346. 授权公告号：CN110483222B，授权公告日：2022.06.21. 申请人：浙江工业大学.[1]  佘远斌, 胡梦云, 沈海民. 一种异丙苯类化合物选择性氧化的方法[P]. 申请号：2019108011327, 申请日：2019.08.28. 申请公布号：CN110423185A, 申请公布日：2019.11.08. 专利号: 2019108011327. 授权公告号：CN110423185B，授权公告日：2022.03.18. 申请人：浙江工业大学. 教学与课程 1.  主讲本科生专业必修课程，《化工安全与环境》2.  主讲本科生专业必修课程，《绿色化工技术》3.  主讲本科生专业选修课程，《化工设计B》4.  辅讲本科生专业必修课程，《化工安全与环境》5.  辅讲本科生专业必修课程，《绿色化学原理与应用》6.  担任绿色化学教研室主任 育人成果 1. 2013-2014年，浙江工业大学校优秀班主任2. 2015年，指导学生获第七届浙江省大学生化学竞赛一等奖3.  2015年，浙江工业大学优秀教师4.  2016年，指导硕士研究生周文杰，获优秀研究生国家奖学金5.  2020年，指导硕士研究生王雄，获优秀研究生国家奖学金6.  2021年，指导硕士研究生吕东，获优秀研究生国家奖学金7.  2022年，浙江工业大学优秀本科毕业论文指导教师8.  2023年，浙江工业大学优秀本科毕业论文指导教师 科研项目 1.  环糊精-Fe3O4超分子仿生催化体系的构筑及其对水相不对称反应的调控，国家自然科学基金青年基金项目，2013.01.01 -2016.12.31，主持2.  双金属卟啉协同催化氧气选择性氧化环烷烃合成醇、酮研究，国家自然科学基金面上项目，2019.01.01-2022.12.31，主持3.  限域环境中双金属中心接力催化O2选择氧化烃类C-H键规律的研究，国家自然科学基金面上项目，2022.01.01- 2025.12.31，主持4.  一种防晒剂A二钠盐合成工艺的开发，企业横向课题，75.0万，主持5.  无水家用机洗洗衣液配方的研究和开发，企业横向课题，5.0万，主持6.  关键医药中间体的工艺研发，企业横向课题，100.0万，主持7.  电化铝烫印箔水溶性色料配方开发和涂布工艺改进，企业横向课题，10.0万，主持 科研成果 学术论文：[39] Yuan-Bin She, Yu Zhang, Jia-Ye Ni, Xin-Yan Zhou, Hong-Liang Ye, Hai-Min Shen*. Practical and efficient oxygenation of benzylic C-H bonds with dioxygen catalyzed by two-dimensional porous organic frameworks possessing porphyrin cobalt(II) units [J]. Chemical Engineering Science, 2024, 293: 120056.[38] Yu Zhang, Bo Fu, Jing Sun, Yan-Bo Ding, Hai-Min Shen*, Yuan-Bin She*. Relay catalysis on the surface of hybrid silica functionalized with dual metalloporphyrins(Co&Zn) for efficient and selective oxygenation of cycloalkanes using oxygen [J]. Molecular Catalysis, 2024, 557: 113957.[37] Xin-Yan Zhou, Bo Fu, Wen-Dong Jin, Xiong Wang, Ke-Ke Wang , Mei Wang, Yuan-Bin She, Hai-Min Shen*. Efficient and Selective Oxygenation of Cycloalkanes and Alkyl Aromatics with Oxygen through Synergistic Catalysis of Bimetallic Active Centers in Two-Dimensional Metal-Organic Frameworks Based on Metalloporphyrins [J]. Biomimetics, 2023, 8(3): 325.[36] Jia-Ye Ni, Bin He, Hao Huang, Lei Ning, Qiu-Ping Liu, Ke-Ke Wang, Hong-Ke Wu, Hai-Min Shen*, Yuan-Bin She*. Cycloalkanes oxidation with O2 in high-efficiency and high-selectivity catalyzed by 3D MOFs with limiting domain and Zn(AcO)2 through synergistic mode [J]. Molecular Catalysis, 2023, 540: 113027.[35] Xin-Yan Zhou, Bin He, Yu Zhang, Jia-Ye Ni, Qiu-Ping Liu, Mei Wang, Hai-Min Shen*, Yuan-Bin She*. Selective and Efficient Catalytic Oxygenation of Alkyl Aromatics Employing H2O2 Catalyzed by Simple Porphyrin Iron(II) under Mild Conditions [J]. Processes, 2023, 11: 1187.[34] Hai-Min Shen, Hong-Liang Ye, Jia-Ye Ni, Ke-Ke Wang, Xin-Yan Zhou, Yuan-Bin She*. Oxidation of α-C-H bonds in alkyl aromatics with O2 catalyzed by highly dispersed cobalt(II) coordinated in confined reaction channel of porphyrin-based POFs with simultaneously enhanced conversion and selectivity [J]. Chemical Engineering Science, 2023, 270: 118472.[33] A-Bing Guo, Jia-Wei Qin, Ke-Ke Wang, Qiu-Ping Liu, Hong-Ke Wu, Mei Wang, Hai-Min Shen*, Yuan-Bin She. Synergetic catalytic oxidation of C-H bonds in cycloalkanes and alkyl aromatics by dimetallic active sites in 3D metalloporphyrinic MOFs employing O2 as oxidant with increased conversion and unconsumed selectivity [J]. Molecular Catalysis, 2023, 535:112853.[32] Hai-Min Shen, Xiong Wang, Hao Huang, Qiu-Ping Liu, Dong Lv, Yuan-Bin She*. Staged oxidation of hydrocarbons with simultaneously enhanced conversion and selectivity employing O2 as oxygen source catalyzed by 2D metalloporphyrin-based MOFs possessing bimetallic active centers [J]. Chemical Engineering Journal, 2022, 443: 136126.[31] Hai-Min Shen, A-Bing Guo, Yu Zhang, Qiu-Ping Liu, Jia-Wei Qin, Yuan-Bin She*. Relay catalysis of hydrocarbon oxidation using O2 in the confining domain of 3D metalloporphyrin-based metal-organic frameworks with bimetallic catalytic centers [J]. Chemical Engineering Science, 2022, 260: 117825.[30] Jia-Ye Ni, Shu-Zhen Cong, Lei Ning, Mei Wang, Hai-Min Shen*, Yuan-Bin She*. Binary catalytic systems constructed by porphyrin cobalts(II) with confining nano-region and Zn(OAc)2 for oxygenation of cycloalkanes with O2 in relay mode [J]. Molecular Catalysis, 2022, 531:112676.[29] Hai-Min Shen, Xiong Wang, Lei Ning, A-Bing Guo, Jin-Hui Deng, Yuan-Bin She*. Efficient        oxidation of cycloalkanes with simultaneously increased conversion and selectivity using O2 catalyzed by metalloporphyrins and boosted by Zn(AcO)2: A practical strategy to inhibit the formation of aliphatic diacids [J]. Applied Catalysis A, General, 2021, 609: 117904.[28] Hai-Min Shen, Hong-Liang Ye, Qin Wang, Meng-Yun Hu, Lei Liu, Yuan-Bing She*. Efficient oxidation of cumene to cumene hydroperoxide with ambient O2 catalyzed by metalloporphyrins [J]. Journal of Porphyrins and Phthalocyanines, 2021, 25: 314-322.[27] Hai-Min Shen, Meng-Yun Hu, Lei Liu, Bei Qi, Hong-Liang Ye, Yuan-Bin She*. Efficient and selective oxidation of tertiary benzylic C-H bonds with O2 catalyzed by metalloporphyrins under mild and solvent-free conditions [J]. Applied Catalysis A, General, 2020, 599: 117599.[26] Hai-Min Shen, Bei Qi, Meng‑Yun Hu, Lei Liu, Hong‑Liang Ye, Yuan‑Bin She*. Selective Solvent-Free and Additive-Free Oxidation of Primary Benzylic C-H Bonds with O2 Catalyzed by the Combination of Metalloporphyrin with N‑Hydroxyphthalimide [J]. Catalysis Letters, 2020, 150: 3096-3111.[25] Hai-Min Shen*, Lei Liu, Bei Qi, Meng-Yun Hu, Hong-Liang Ye, Yuan-Bin She. Efficient and selective oxidation of secondary benzylic C-H bonds to ketones with O2 catalyzed by metalloporphyrins under solvent-free and additive-free conditions [J]. Molecular Catalysis, 2020, 493: 111102.[24] Hai-Min Shen, Xiong Wang, A-Bing Guo, Long Zhang, Yuan-Bing She*. Catalytic oxidation of cycloalkanes by porphyrin cobalt(II) through efficient utilization of oxidation intermediates [J]. Journal of Porphyrins and Phthalocyanines, 2020, 24: 1166-1173.[23] Hai-Min Shen, Long Zhang, Jin-Hui Deng, Jing Sun, Yuan-Bin She*. Enhanced catalytic performance of porphyrin cobalt(II) in the solvent-free oxidation of cycloalkanes (C5~C8) with molecular oxygen promoted by porphyrin zinc(II) [J]. Catalysis Communications, 2019, 132: 105809 .[22] Hai-Min Shen, Yan Wang, Jin-Hui Deng, Long Zhang, Yuan-Bin She*. Catalyst-free and solvent-free oxidation of cycloalkanes (C5-C8) with molecular oxygen: Determination of autoxidation temperature and product distribution[J]. Chinese Journal of Chemical Engineerin，2018，26(5)：1064-1070.[21] 佘远斌，邓金辉，张龙，沈海民*. 氧气催化氧化环己烷[J].化学进展，2018，30(1)：124-136.[20] 沈海民，王岩，佘远斌*.金属卟啉催化氧化环己烷最新研究进展[J].化工进展，2018，37(6)：2031-2045.[19] 韩叶强，周文杰，沈海民*，刘秋平，于文艳，纪红兵，佘远斌*.固载化β-环糊精吸附环境污染物的研究进展[J].有机化学，2016，36(2)：248-257.[18] Hai-Min Shen*，Wen-Jie Zhou，Wu-Bin Yu，Hong-Ke Wu，Qiu-Ping Liu，Hong-Bing Ji，Yan Wang，Yuan-Bin She*.Metal-free chemoselective oxidation of sulfides to sulfoxides catalyzed by immobilized L-aspartic acid and L-glutamic acid in an aqueous phase at room temperature[J].New Journal of Chemistry，2016，40(6)：4874-4878.[17] 沈海民*，武宏科，史鸿鑫，纪红兵，余武斌*.非均相环糊精在水相有机合成反应中的应用[J].化学进展，2015，27(1)：70-78.[16] 沈海民*，方红果，武宏科，纪红兵，史鸿鑫*.环糊精衍生物的分子形态及其构筑策略研究进展[J].化工进展，2015，34(2)：430-446.[15] Hai-Min Shen*，Wen-Jie Zhou，Hong-Ke Wu，Wu-Bin Yu，Ning Ai，Hong-Bing Ji，Hong-Xin Shi，Yuan-Bin She*.Metal-free chemoselective oxidation of sulfides to sulfoxides catalyzed by immobilized taurine and homotaurine in aqueous phase at room temperature[J].Tetrahedron Letters，2015，56(30)：4494-4498.[14] Hai-Min Shen*，Wen-Jie Zhou，Xin Ma，Hong-Ke Wu，Wu-Bin Yu，Ning Ai，Hong-Bing Ji，Hong-Xin Shi， Yuan-Bin She*.pH-Dependence of the Aqueous Phase Room Temperature Brønsted Acid-Catalyzed Chemoselective Oxidation of Sulfides with H2O2[J].Molecules，2015，20(9)：16709-16722.[13] Hai-Min Shen，Gong-Yuan Zhu，Wu-Bin Yu，Hong-Ke Wu，Hong-Bing Ji，   Hong-Xin Shi，Yi-Fan Zheng*，Yuan-Bin She*.Surface immobilization of β-cyclodextrin on hybrid silica and its fast adsorption performance of p-nitrophenol from the aqueous phase[J].RSC Advances，2015，5(103)：84410-84422. [12] Hai-Min Shen*，Gong-Yuan Zhu，Wu-Bin Yu，Hong-Ke Wu，Hong-Bing Ji，Hong-Xin Shia，Yuan-Bin She，Yi-Fan Zheng.Fast adsorption of p-nitrophenol from aqueous solution using β-cyclodextrin grafted silica gel[J].Applied Surface Science，2015，356：1155-1167.[11] 沈海民*，武宏科，纪红兵，史鸿鑫*. β-环糊精-Fe3O4超分子体系的构筑及其应用研究进展[J].有机化学，2014，34(4)：630-646.[10] 沈海民*，纪红兵，武宏科，史鸿鑫*.β-环糊精的固载及其应用最新研究进展[J].有机化学，2014，34(8)：1549-1572.[9] Hai-Min Shen，Hong-Bing Ji*. Cyclodextrine-[RuCl2(Arene)]2 conjugates: another  way to enhancethe enantioselectivity of aromatic ketones reduction by aromatic ligands’ volume[J].Tetrahedron，2013，69(39)：8360-8367.[8] Hai-Min Shen，Hong-Bing Ji*.Amino alcohol-modified β-cyclodextrin inducing biomimetic asymmetric oxidation of thioanisole in water[J].Carbohydrate Research，2012，354：49-58.[7] 沈海民，纪红兵*.环糊精衍生物在金属催化有机合成中的应用[J].有机化学，2012，32(6)：975-985.[6] Hai-Min Shen，Hong-Bing Ji*.Biomimetic asymmetric aldol reactions catalyzed by proline derivatives attached to β-cyclodextrin in water[J].Tetrahedron Letters，2012，53(28)：3541-3545.[5] 沈海民，纪红兵*. β-环糊精衍生物诱导Na2MoO4催化H2O2不对称氧化苯甲硫醚[J].有机化学，2012，32(9)：1684-1689.[4] 沈海民，纪红兵*.环糊精衍生物在液相有机合成中的应用[J].有机化学，2011，31(6)：791-803.[3] 沈海民，史鸿鑫*，武宏科，项菊萍，朱春凤.N-(p-全氟壬烯氧基苯磺酰基)肌氨酸钠的合成与表面活性[J]. 高校化学工程学报，2009，23(4)：679-683.[2] 沈海民，史鸿鑫*，项菊萍，刘秋平，朱春凤.硫酸酯型氟表面活性剂的合成与表面活性[J].应用化学，2009，26(9)：1036-1039.[1] 沈海民，史鸿鑫*，武宏科，项菊萍.对全氟壬烯氧基苯磺酸钠的合成与表面活性[J].农药，2007，46(8)：520-522.授权专利：[12] 沈海民，张羽，孙静. 一种双金属中心金属卟啉及其制备方法和应用[P]. 申请号：202010884408.5, 申请日：2020.08.28. 申请公布号：CN112090449A, 申请公布日：2020.12.18. 授权公告号：CN112090449B，专利号：ZL 202010884408.5，授权公告日：2023.03.31. 申请人：浙江工业大学.[11] 沈海民，黄浩. 一种三金属中心(Co&Cu&Zn)2DMOFs/紫外光催化氧化环烷烃的方法[P]. 申请号：202111006432.X, 申请日：2021.08.30. 申请公布号：CN113603564A, 申请公布日：2021.11.05. 授权公告号：CN113603564B，专利号：ZL 202111006432.X，授权公告日：2023.03.14. 申请人：浙江工业大学.[10] 沈海民，黄浩. 一种金属卟啉三金属中心2DMOFs及其制备方法和应用[P]. 申请号：202111008838.1, 申请日：2021.08.31. 申请公布号：CN113683619A, 申请公布日：2021.11.23. 授权公告号：CN113683619B，专利号：ZL 202111008838.1,授权公告日：2023.07.14. 申请人：浙江工业大学.[9] Hai-Min Shen, Lei Ning, Yuan-Bin She. Confined Porphyrin Co(II) and Preparation Method and Application Thereof [P].  Patent No.: US11420991(B2), Date of Patent: 2022-08-23. Applicant: Zhejiang University of Technology.[8]  沈海民，任文山. 一种Cu(II)/硝酸二元催化体系催化O2氧化环己烯一步合成己二酸的方法[P]. 申请号：2021109811098, 申请日：2021.08.25. 申请公布号：CN113563176A, 申请公布日：2021.10.29. 专利号：ZL 2021109811098，授权公告号：CN113563176B，授权公告日：2022.12.20. 申请人：浙江工业大学.[7]  沈海民，丛淑贞. 封端3D钴(II)卟啉POF材料及其制备方法和应用[P]. 申请号：2021109875009, 申请日：2021.08.26. 申请公布号：CN113717394A, 申请公布日：2021.11.30. 专利号: 2021109875009. 授权公告号：CN113717394B，授权公告日：2022.06.03. 申请人：浙江工业大学.[6]  沈海民，宁磊，佘远斌. 一种限域性卟啉Co(II)及其制备方法和应用[P]. 申请号：2019111619249, 申请日：2019.11.25. 申请公布号：CN110938078A, 申请公布日：2020.03.31. 专利号: 2019111619249. 授权公告号：CN110938078B，授权公告日：2021.01.01. 申请人：浙江工业大学.[5]  沈海民，齐备，佘远斌. 甲苯类化合物选择性氧化的方法[P]. 申请号：2019108011331, 申请日：2019.08.28. 申请公布号：CN110563590A, 申请公布日：2019.12.13. 专利号: 2019108011331. 授权公告号：CN110563590B，授权公告日：2022.03.18. 申请人：浙江工业大学.[4]  沈海民, 叶宏亮, 佘远斌. 一种乙苯及其衍生物选择性氧化制备苯乙酮及其衍生物的方法[P]. 申请号：2019107949087, 申请日：2019.08.27. 申请公布号：CN110498745A, 申请公布日：2019.11.26. 专利号: 2019107949087. 授权公告号：CN110498745B，授权公告日：2022.06.17. 申请人：浙江工业大学.[3]  沈海民, 史鸿鑫, 武宏科. 一种不锈钢氧化层清洗剂及其制备方法和应用[P]. 申请号：2014100424102, 申请日：2014.01.28. 申请公布号：CN103820797A, 申请公布日: 2014.05.28. 申请人：浙江工业大学. 授权专利号: 2014100424102, 授权公告号: CN103820797B, 授权日: 2016.05.18.[2]  佘远斌, 刘磊, 沈海民. 一种乙苯类化合物选择性氧化的方法[P]. 申请号：2019108011346, 申请日：2019.08.28. 申请公布号：CN110483222A, 申请公布日：2019.11.22. 专利号: 2019108011346. 授权公告号：CN110483222B，授权公告日：2022.06.21. 申请人：浙江工业大学.[1]  佘远斌, 胡梦云, 沈海民. 一种异丙苯类化合物选择性氧化的方法[P]. 申请号：2019108011327, 申请日：2019.08.28. 申请公布号：CN110423185A, 申请公布日：2019.11.08. 专利号: 2019108011327. 授权公告号：CN110423185B，授权公告日：2022.03.18. 申请人：浙江工业大学. 社会服务 2018年08月-2019年07月，山东省滕州市官桥镇副镇长，挂职